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Acetamide is treated separately with the...

Acetamide is treated separately with the following reagents. Which one of these would give methyl amine ?

A

`NaOH//Br_(2)`

B

Sodalime

C

Hot conc. `H_(2)SO_(4)`

D

`PCl_(5)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reagent will convert acetamide to methyl amine, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Acetamide**: Acetamide has the chemical structure CH₃C(=O)NH₂. It consists of a carbonyl group (C=O) attached to an amine group (NH₂). 2. **Understand the Reaction Type**: The reaction we are interested in is known as the Hofmann degradation reaction. This reaction involves the conversion of an amide to a primary amine with the loss of one carbon atom. 3. **Identify the Reagents**: The reagents typically used in the Hofmann degradation reaction are sodium hydroxide (NaOH) and bromine (Br₂). 4. **Write the Reaction**: When acetamide reacts with NaOH and Br₂, the carbonyl carbon is eliminated, leading to the formation of methyl amine (CH₃NH₂) and sodium bromide (NaBr) as a byproduct. The reaction can be summarized as: \[ \text{CH}_3\text{C(=O)NH}_2 + \text{NaOH} + \text{Br}_2 \rightarrow \text{CH}_3\text{NH}_2 + \text{NaBr} + \text{H}_2\text{O} \] 5. **Conclusion**: Therefore, the reagent that will give methyl amine when acetamide is treated is **NaOH and Br₂**. ### Final Answer: The correct reagent that will convert acetamide to methyl amine is **NaOH and Br₂** (Option A).

To determine which reagent will convert acetamide to methyl amine, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Structure of Acetamide**: Acetamide has the chemical structure CH₃C(=O)NH₂. It consists of a carbonyl group (C=O) attached to an amine group (NH₂). 2. **Understand the Reaction Type**: ...
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