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In this reaction, CH(3)CHOtoCH(3)CH(OH...

In this reaction,
`CH_(3)CHOtoCH_(3)CH(OH)Cnoverset(H*OH)toCH_(3)CH(OH)COOH`
An asymmetric centre is generated. The acid obtained would be

A

50%D+50% L-isomer

B

20%D+80% L-isomer

C

D-isomer

D

L-isomer

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction step by step and identify the final product formed, which is an acid. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The reaction starts with an aldehyde, specifically acetaldehyde (CH₃CHO). 2. **Reaction with HCN**: The acetaldehyde undergoes a reaction with hydrogen cyanide (HCN). This reaction leads to the formation of a cyanohydrin. The reaction can be represented as: \[ CH₃CHO + HCN \rightarrow CH₃C(OH)(CN)H \] Here, the cyanide (CN) group adds to the carbonyl carbon, and a hydroxyl (OH) group is also attached. 3. **Formation of an Asymmetric Center**: The product formed (CH₃C(OH)(CN)H) has a chiral center because it has four different groups attached to the carbon atom that bears the hydroxyl group (OH). This results in the formation of two enantiomers: D-isomer and L-isomer. 4. **Hydrolysis of the Cyanohydrin**: The next step involves hydrolysis of the cyanohydrin. When the cyanohydrin is hydrolyzed, the cyanide group (CN) is converted into a carboxylic acid (COOH). The reaction can be represented as: \[ CH₃C(OH)(CN)H + H₂O \rightarrow CH₃C(OH)COOH \] The product formed here is lactic acid (CH₃C(OH)COOH). 5. **Final Product**: The final product of the reaction is lactic acid, which exists as a racemic mixture of D-lactic acid and L-lactic acid. This means that there are equal amounts (50% each) of the two enantiomers. ### Conclusion: The acid obtained from the reaction is **lactic acid (CH₃C(OH)COOH)**.

To solve the problem, we need to analyze the reaction step by step and identify the final product formed, which is an acid. ### Step-by-Step Solution: 1. **Identify the Starting Material**: The reaction starts with an aldehyde, specifically acetaldehyde (CH₃CHO). 2. **Reaction with HCN**: ...
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