Home
Class 12
CHEMISTRY
(CH(3))(3) C - CHO does not undergo aldo...

`(CH_(3))_(3) C - CHO` does not undergo aldol condensation due to

A

three electron donating methyl groups

B

cleavage takig palce between `-C-CHO` bond

C

absence of alpha hydrogen atom in the molecule

D

bulky `(CH_(3))_(3)C-` group

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding why `(CH₃)₃C - CHO` does not undergo aldol condensation, we can follow these steps: ### Step 1: Understand Aldol Condensation Aldol condensation is a reaction between aldehydes or ketones that contain at least one alpha hydrogen atom. The reaction involves the formation of a beta-hydroxy aldehyde or ketone, which can further dehydrate to form an α,β-unsaturated carbonyl compound. ### Step 2: Identify the Compound The given compound is `(CH₃)₃C - CHO`, which is known as isobutyraldehyde. The structure can be represented as: ``` CH₃ | CH₃ - C - CHO | CH₃ ``` ### Step 3: Locate the Alpha Carbon In the structure of isobutyraldehyde, the carbon atom adjacent to the carbonyl group (CHO) is the alpha carbon. ### Step 4: Check for Alpha Hydrogen Atoms For aldol condensation to occur, the alpha carbon must have at least one hydrogen atom attached to it. In this case, the alpha carbon is attached to three methyl groups (CH₃). Therefore, it does not have any hydrogen atoms attached to it. ### Step 5: Conclusion Since the alpha carbon does not have any hydrogen atoms (alpha hydrogen), the compound `(CH₃)₃C - CHO` cannot participate in aldol condensation. Thus, the reason for the non-reactivity in aldol condensation is the **absence of alpha hydrogen atoms**. ### Final Answer The compound `(CH₃)₃C - CHO` does not undergo aldol condensation due to the **absence of alpha hydrogen atoms** on the alpha carbon. ---

To solve the question regarding why `(CH₃)₃C - CHO` does not undergo aldol condensation, we can follow these steps: ### Step 1: Understand Aldol Condensation Aldol condensation is a reaction between aldehydes or ketones that contain at least one alpha hydrogen atom. The reaction involves the formation of a beta-hydroxy aldehyde or ketone, which can further dehydrate to form an α,β-unsaturated carbonyl compound. ### Step 2: Identify the Compound The given compound is `(CH₃)₃C - CHO`, which is known as isobutyraldehyde. The structure can be represented as: ``` ...
Promotional Banner

Similar Questions

Explore conceptually related problems

What type of aldehydes undergo Aldol condensation ?

CH_(3)-CHOoverset(veC CH)rarrCH_(3)CH(OH)CH_(2)CHO In the aldol condensation of acetaldehyde represented above, which of the following intermediate species as obtained?

The diketone CH_(3)-overset(overset(O)(||))(C)-(CH_(2))_(2)-overset(overset(O)(||))(C)-CH_(3) on intermolecular aldol condensation gives the final product

Which of the following will not undergo aldol condensation ?

Which of the following will not undergo aldol condensation ?

Aldehydes that do not undergo aldol condensation are (1) propanal (2) trichloroethanal (3) 2- phenylethanal (4) ethanal (5) benzaldehyde

Which of the following will not undergo aldol condensation-

Which of the following will undergo aldol condensation ?

Which of the following will not undergo aldol condensation-