Home
Class 12
CHEMISTRY
Correct order of stability is:...

Correct order of stability is:

A

1- butene `gt` Trans-2- butene `gt` Cis -2- butene

B

Trans-2-butene`gt`1-butene `gt` cis-2-butene

C

Trans-2-butene `gt` cis--2-butene `gt` 1-butene

D

Cis-2-butene `gt` Trans-2-butene`gt` 1 butene

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of stability among 1-butene, cis-2-butene, and trans-2-butene, we can analyze the structures and stability factors of these alkenes step by step. ### Step 1: Draw the Structures 1. **1-butene**: This is a straight-chain alkene with the double bond between the first and second carbon atoms. Its structure is: ``` CH2=CH-CH2-CH3 ``` 2. **cis-2-butene**: This alkene has the double bond between the second and third carbon atoms, with the two methyl groups (CH3) on the same side. Its structure is: ``` CH3 | CH3-CH=CH-CH2 ``` 3. **trans-2-butene**: Similar to cis-2-butene, but the two methyl groups are on opposite sides of the double bond. Its structure is: ``` CH3 | CH2=CH-CH3 ``` ### Step 2: Analyze Stability Factors - **Hyperconjugation**: This is a stabilizing interaction that occurs when alkyl groups donate electron density through the σ-bonds to the adjacent π-bond. The more alkyl groups attached to the double bond, the more stable the alkene. - **Steric Hindrance**: In alkenes, steric hindrance occurs when larger groups are adjacent to each other, which can destabilize the molecule. In general, trans alkenes are more stable than cis alkenes due to reduced steric hindrance. ### Step 3: Compare the Stability 1. **1-butene**: It has only two alpha hydrogens (hydrogens on the carbons adjacent to the double bond) and thus has limited hyperconjugation. This makes it the least stable alkene. 2. **cis-2-butene**: It has four alpha hydrogens, which allows for more hyperconjugation than 1-butene. However, due to steric hindrance from the adjacent methyl groups, it is less stable than trans-2-butene. 3. **trans-2-butene**: It has the same number of alpha hydrogens as cis-2-butene (four), but the methyl groups are on opposite sides of the double bond, reducing steric hindrance. This makes trans-2-butene the most stable alkene among the three. ### Conclusion Based on the analysis: - **Most Stable**: trans-2-butene - **Moderately Stable**: cis-2-butene - **Least Stable**: 1-butene Thus, the correct order of stability is: **trans-2-butene > cis-2-butene > 1-butene** ### Final Answer The correct order of stability is: **trans-2-butene > cis-2-butene > 1-butene**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Determine the correct order of stability :-

Which of the following is correct order of stability:

Correct order of stability of following alkenes is

Correct order of stability of species N_(2),N_(2)^(+),N_(2)^(-)

Arange the following in correct order of stability. (i) Ga' In, TI' (ii) As^(+5),Sb^(+5), B^(+5)

Consider the following carbanions (i) CH_(3)- overset(Ө)CH_(2)" "(ii) CH_(2) = overset(Ө)CH" "(iii) CH -= overset(Ө)C Correct order of stability of these carbanions in decreasing order is

The correct order of stability for the following alkoxides is :

Which is correct order of stability of carbanions ?