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For the reaction H^(+) + BrO(3)^(-) + 3 ...

For the reaction `H^(+) + BrO_(3)^(-) + 3 Br^(-) to 5 Br_(2) + H_(2) O` which of the following relation correctly represents the consumption & formation of reactants and products:

A

`(d[Br^(-)])/(dt) = (3)/(5)(d[Br_(2)])/(dt)`

B

`(d[Br^(-)])/(dt) = - (3)/(5) (d[Br_(2)])/(dt)`

C

`(d[Br^(-)])/(dt) = - (5)/(3) (d[Br_(2)])/(dt)`

D

`(d[Br^(-)])/(dt) = (5)/(3) (d[Br_(2)])/(dt)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given chemical reaction and derive the correct relationship between the consumption and formation of reactants and products. The reaction is: \[ H^+ + BrO_3^- + 3 Br^- \rightarrow 5 Br_2 + H_2O \] ### Step-by-Step Solution: 1. **Identify the Reaction Components**: - Reactants: \( H^+, BrO_3^-, 3 Br^- \) - Products: \( 5 Br_2, H_2O \) 2. **Write the General Rate Expression**: For a general reaction: \[ aA + bB \rightarrow cC + dD \] The rate of the reaction can be expressed in terms of the change in concentration of reactants and products: \[ -\frac{1}{a} \frac{d[A]}{dt} = -\frac{1}{b} \frac{d[B]}{dt} = \frac{1}{c} \frac{d[C]}{dt} = \frac{1}{d} \frac{d[D]}{dt} \] 3. **Apply to the Given Reaction**: For our specific reaction: - For \( Br^- \): The stoichiometric coefficient is 3, so: \[ -\frac{1}{3} \frac{d[Br^-]}{dt} \] - For \( Br_2 \): The stoichiometric coefficient is 5, so: \[ \frac{1}{5} \frac{d[Br_2]}{dt} \] 4. **Set Up the Rate Equation**: From the above expressions, we can equate the rates: \[ -\frac{1}{3} \frac{d[Br^-]}{dt} = \frac{1}{5} \frac{d[Br_2]}{dt} \] 5. **Rearranging the Equation**: To express \( \frac{d[Br^-]}{dt} \) in terms of \( \frac{d[Br_2]}{dt} \): \[ \frac{d[Br^-]}{dt} = -\frac{3}{5} \frac{d[Br_2]}{dt} \] 6. **Final Expression**: The final relationship we derived is: \[ \frac{d[Br^-]}{dt} = -\frac{3}{5} \frac{d[Br_2]}{dt} \] ### Conclusion: The correct option that represents the consumption and formation of reactants and products is: **Option B: \( \frac{d[Br^-]}{dt} = -\frac{3}{5} \frac{d[Br_2]}{dt} \)**.
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