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Which of the following shows maximum num...

Which of the following shows maximum number of oxidation states :-

A

Cr

B

Fe

C

Mn

D

V

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given elements shows the maximum number of oxidation states, we will analyze the valence electronic configurations of each element and calculate their possible oxidation states. ### Step-by-Step Solution: 1. **Identify the Elements and Their Electronic Configurations:** - Chromium (Cr): [Ar] 3d⁵ 4s¹ - Iron (Fe): [Ar] 3d⁶ 4s² - Manganese (Mn): [Ar] 3d⁵ 4s² - Promethium (Pm): [Xe] 4f⁵ 6s² 2. **Calculate Oxidation States for Each Element:** - **Chromium (Cr):** - Can lose 1 electron from 4s: +1 - Can lose 2 electrons (1 from 4s and 1 from 3d): +2 - Can lose 3 electrons (2 from 4s and 1 from 3d): +3 - Can lose 4 electrons (3 from 3d): +4 - Can lose 5 electrons (4 from 3d): +5 - Can lose 6 electrons (5 from 3d): +6 - Total oxidation states: +1, +2, +3, +4, +5, +6 (6 oxidation states) - **Iron (Fe):** - Can lose 2 electrons from 4s: +2 - Can lose 3 electrons (2 from 4s and 1 from 3d): +3 - Can lose 4 electrons (3 from 3d): +4 - Can lose 5 electrons (4 from 3d): +5 - Can lose 6 electrons (5 from 3d): +6 - Total oxidation states: +2, +3, +4, +5, +6 (5 oxidation states) - **Manganese (Mn):** - Can lose 2 electrons from 4s: +2 - Can lose 3 electrons (2 from 4s and 1 from 3d): +3 - Can lose 4 electrons (3 from 3d): +4 - Can lose 5 electrons (4 from 3d): +5 - Can lose 6 electrons (5 from 3d): +6 - Can lose 7 electrons (6 from 3d): +7 - Total oxidation states: +2, +3, +4, +5, +6, +7 (7 oxidation states) - **Promethium (Pm):** - Typically exhibits oxidation states of +3 and +4. - Total oxidation states: +3, +4 (2 oxidation states) 3. **Compare the Number of Oxidation States:** - Chromium: 6 oxidation states - Iron: 5 oxidation states - Manganese: 7 oxidation states - Promethium: 2 oxidation states 4. **Conclusion:** - Manganese shows the maximum number of oxidation states, which is 7. ### Final Answer: **Manganese (Mn) shows the maximum number of oxidation states.**
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