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Using anhydrous AlCl(3) as catalyst, whi...

Using anhydrous `AlCl_(3)` as catalyst, which one of the following reactions produces ethylbenzene `(PhEt)` ?

A

`CH_3-CH=CH_2+C_6H_6`

B

`H_2C=CH_2+C_6H_6`

C

`H_3C-CH_3+C_6H_6`

D

`H_3C-CH_2OH+C_6H_6`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which reaction produces ethylbenzene (PhEt) using anhydrous AlCl₃ as a catalyst, we will analyze each option provided in the question. ### Step 1: Understanding the Reactions Anhydrous AlCl₃ is a Lewis acid catalyst commonly used in Friedel-Crafts alkylation reactions, where an alkene reacts with benzene to form an alkyl-substituted benzene. ### Step 2: Evaluating Each Option - **Option A: Propene with Benzene** - Propene (C₃H₆) can react with benzene in the presence of AlCl₃. The reaction will produce isopropylbenzene (cumene) rather than ethylbenzene. - **Option B: Ethene with Benzene** - Ethene (C₂H₄) reacts with benzene in the presence of AlCl₃ to form ethylbenzene (C₆H₅C₂H₅). This is the correct reaction that produces the desired product. - **Option C: Ethane with Benzene** - Ethane (C₂H₆) does not react with benzene in the presence of AlCl₃. This reaction does not occur because ethane is not an alkene and cannot form a carbocation. - **Option D: Ethyl Alcohol with Benzene** - Ethyl alcohol (C₂H₅OH) does not react with benzene in the presence of AlCl₃ to form ethylbenzene. This reaction does not occur as well. ### Conclusion The correct answer is **Option B: Ethene with Benzene**, which produces ethylbenzene when reacted in the presence of anhydrous AlCl₃. ### Final Answer **Option B: Ethene with Benzene produces ethylbenzene (PhEt).** ---
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