Home
Class 12
CHEMISTRY
For a first-order reaction A rarr B the ...

For a first-order reaction `A rarr B` the reaction rate at reactant concentration of `0.10 M` is found to be `2.0 xx 10^(-5) "mol" L^(-1) s^(-1)`. The half-life period of the reaction is

Text Solution

AI Generated Solution

The correct Answer is:
To find the half-life period of a first-order reaction \( A \rightarrow B \), we can follow these steps: ### Step 1: Understand the relationship between rate, concentration, and rate constant For a first-order reaction, the rate of the reaction is given by the equation: \[ \text{Rate} = k[A] \] where \( k \) is the rate constant and \([A]\) is the concentration of the reactant. ### Step 2: Substitute the given values into the rate equation We are given: - Rate = \( 2.0 \times 10^{-5} \, \text{mol L}^{-1} \text{s}^{-1} \) - Concentration \([A] = 0.10 \, \text{M}\) Substituting these values into the rate equation: \[ 2.0 \times 10^{-5} = k \times 0.10 \] ### Step 3: Solve for the rate constant \( k \) Rearranging the equation to solve for \( k \): \[ k = \frac{2.0 \times 10^{-5}}{0.10} = 2.0 \times 10^{-4} \, \text{s}^{-1} \] ### Step 4: Use the formula for half-life of a first-order reaction The half-life \( t_{1/2} \) for a first-order reaction is given by the formula: \[ t_{1/2} = \frac{0.693}{k} \] ### Step 5: Substitute the value of \( k \) into the half-life formula Now substituting \( k = 2.0 \times 10^{-4} \, \text{s}^{-1} \): \[ t_{1/2} = \frac{0.693}{2.0 \times 10^{-4}} = 3465 \, \text{s} \] ### Step 6: Round the answer Rounding \( 3465 \, \text{s} \) gives approximately \( 3465 \, \text{s} \). ### Final Answer The half-life period of the reaction is approximately \( 3465 \, \text{s} \). ---
Promotional Banner

Similar Questions

Explore conceptually related problems

For a first-order reaction A rarr B the reaction rate at reactant concentration of 0.01 M is found to be 2.0 xx 10^(-5) "mol" L^(-1) s^(-1) . The half-life period of the reaction is

For a first order reaction A to B the reaction rate at reactant concentration of 0.01 M is found to be 2.0 xx 10 ^-5mol L^(-1) s^(-1) . The half-life period of the reaction is

For a first-order reaction; A → B, the reaction rate at a reactant concentration of 0.01 M is found to be 3.0×10^(−5) mol L^(−1) s^(−1) . The half-life period of the reaction is:

For a first order reaction A→B, the reaction rate at reactant concentration of 0.01 M is found to be 2.0×10^(−5)molL^(−1)s^(−1) .The half-life period of the reaction is:

The rate constant of first order reaction is 10^(-2)"min"^(-1) . The half-life period of reaction is

For a first order for the reaction A rarr products : the rate of reaction at [A]=0.2 M is 1.0 xx 10^(-3) mol L^(-1)s^(-1) . The reaction will occur to 75% completion in .

For a first order reaction the rate constant for decomposition of N_(2)O is 6xx10^(-4)sec^(-1) . The half-life period for the decomposition in seconds is :

A first order reaction is found to have a rate constant k= 5.5 xx 10^(-14)s^(-1) . Find half-life of the reaction.