Home
Class 12
CHEMISTRY
Four diatomic species are listed in dif...

Four diatomic species are listed in different sequence .Which of these represent the correct order of their increasing bond order?

A

`C_(2)^(2-) lt He_(2)^(+) lt NO lt O_(2)^(-)`

B

`He_(2)^(+) lt O_(2)^(-) lt NO lt C_(2)^(2-)`

C

`O_(2)^(-) lt NO lt C_(2)^(2-) lt HE_(2)^(+)`

D

`NO lt C_(2)^(2-) lt O_(2)^(-) lt He_(2)^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order of increasing bond order for the given diatomic species (C2²⁻, He2⁺, NO, and O2⁻), we will calculate the bond order for each species step by step. ### Step 1: Calculate the bond order for C2²⁻ 1. **Electronic Configuration**: - C2²⁻ has 10 electrons: - σ1s², σ*1s², σ2s², σ*2s², π2px², π2py², σ2pz² 2. **Bonding and Antibonding Electrons**: - Bonding electrons: 2 (σ1s) + 2 (σ2s) + 2 (π2px) + 2 (π2py) + 2 (σ2pz) = 10 - Antibonding electrons: 2 (σ*1s) + 2 (σ*2s) = 4 3. **Bond Order Calculation**: - Bond Order = 1/2 (Number of bonding electrons - Number of antibonding electrons) - Bond Order = 1/2 (10 - 4) = 3 ### Step 2: Calculate the bond order for He2⁺ 1. **Electronic Configuration**: - He2⁺ has 1 electron: - σ1s², σ*1s¹ 2. **Bonding and Antibonding Electrons**: - Bonding electrons: 2 (σ1s) = 2 - Antibonding electrons: 1 (σ*1s) = 1 3. **Bond Order Calculation**: - Bond Order = 1/2 (2 - 1) = 0.5 ### Step 3: Calculate the bond order for NO 1. **Electronic Configuration**: - NO has 11 electrons: - σ1s², σ*1s², σ2s², σ*2s², π2px², π2py², σ2pz², π*2px¹ 2. **Bonding and Antibonding Electrons**: - Bonding electrons: 2 (σ1s) + 2 (σ2s) + 2 (π2px) + 2 (π2py) + 2 (σ2pz) = 10 - Antibonding electrons: 2 (σ*1s) + 2 (σ*2s) + 1 (π*2px) = 5 3. **Bond Order Calculation**: - Bond Order = 1/2 (10 - 5) = 2.5 ### Step 4: Calculate the bond order for O2⁻ 1. **Electronic Configuration**: - O2⁻ has 18 electrons: - σ1s², σ*1s², σ2s², σ*2s², σ2pz², π2px², π2py², π*2px², π*2py¹ 2. **Bonding and Antibonding Electrons**: - Bonding electrons: 2 (σ1s) + 2 (σ2s) + 2 (σ2pz) + 2 (π2px) + 2 (π2py) = 10 - Antibonding electrons: 2 (σ*1s) + 2 (σ*2s) + 2 (π*2px) + 1 (π*2py) = 7 3. **Bond Order Calculation**: - Bond Order = 1/2 (10 - 7) = 1.5 ### Summary of Bond Orders - C2²⁻: Bond Order = 3 - He2⁺: Bond Order = 0.5 - NO: Bond Order = 2.5 - O2⁻: Bond Order = 1.5 ### Step 5: Order of Increasing Bond Order Now, we can arrange the bond orders in increasing order: 1. He2⁺ (0.5) 2. O2⁻ (1.5) 3. NO (2.5) 4. C2²⁻ (3) ### Final Answer The correct order of increasing bond order is: **He2⁺ < O2⁻ < NO < C2²⁻**

To determine the correct order of increasing bond order for the given diatomic species (C2²⁻, He2⁺, NO, and O2⁻), we will calculate the bond order for each species step by step. ### Step 1: Calculate the bond order for C2²⁻ 1. **Electronic Configuration**: - C2²⁻ has 10 electrons: - σ1s², σ*1s², σ2s², σ*2s², π2px², π2py², σ2pz² 2. **Bonding and Antibonding Electrons**: - Bonding electrons: 2 (σ1s) + 2 (σ2s) + 2 (π2px) + 2 (π2py) + 2 (σ2pz) = 10 ...
Promotional Banner

Similar Questions

Explore conceptually related problems

The correct order of increasing bond angle is

The correct order of increasing bond angle is

Which of the following is the correct order for increasing bond angle ?

Which of the following represents the correct order of acidity?

Which of the following represents the correct order of acidic strength ?

The correct order of increasing order of size is

Correct order of bond length is

Which of the following represents correct order of evolution?

Which of the following arrangements represents the correct order of increasing radius?

Which of the following represents the correct order of the properties inidicated?