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Which of the following expressions corre...

Which of the following expressions correctly repesents the equivalent conductance at infinte dilution of `Al_(2)(SO_(4))_(3)`. Given that `Lambda_(Al^(3+))^(@)` and `Lambda_(SO_(4)^(2-))^(@)` are the equivalent conductance at infinte dilution of the respective ions?

A

`Lambda_(Al^(3+))^(@)+Lambda_(SO_(4)^(2-))`

B

`(Lambda_(Al^(3+))^(@)+Lambda_(SO_(4)^(2-)))xx6`

C

`(1)/(3)Lambda_(Al^(3+))^(@)+(1)/(2)Lambda_(SO_(4)^(2-))^(@)`

D

`2Lambda_(Al^(3+))^(@)+3Lambda_(SO_(4)^(2-))^(@)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the equivalent conductance at infinite dilution of \( Al_2(SO_4)_3 \), we need to consider how the compound dissociates in solution and the contributions of its ions to the overall conductance. ### Step-by-Step Solution: 1. **Identify the Dissociation of the Compound:** The dissociation of \( Al_2(SO_4)_3 \) in water can be represented as: \[ Al_2(SO_4)_3 \rightarrow 2Al^{3+} + 3SO_4^{2-} \] 2. **Understand Equivalent Conductance:** The equivalent conductance (\( \Lambda \)) at infinite dilution is the sum of the contributions from each ion in solution. For a given ion, it is denoted as \( \Lambda^0 \) (at infinite dilution). 3. **Write the Expression for Equivalent Conductance:** The equivalent conductance at infinite dilution for \( Al_2(SO_4)_3 \) can be expressed as: \[ \Lambda_{Al_2(SO_4)_3}^0 = 2\Lambda_{Al^{3+}}^0 + 3\Lambda_{SO_4^{2-}}^0 \] However, since we are looking for the equivalent conductance, we only consider the contributions of the ions without multiplying by their stoichiometric coefficients. 4. **Final Expression:** Therefore, the equivalent conductance at infinite dilution of \( Al_2(SO_4)_3 \) is given by: \[ \Lambda_{Al_2(SO_4)_3}^0 = 2\Lambda_{Al^{3+}}^0 + 3\Lambda_{SO_4^{2-}}^0 \] ### Conclusion: The correct expression representing the equivalent conductance at infinite dilution of \( Al_2(SO_4)_3 \) is: \[ \Lambda_{Al_2(SO_4)_3}^0 = 2\Lambda_{Al^{3+}}^0 + 3\Lambda_{SO_4^{2-}}^0 \]
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