Home
Class 12
CHEMISTRY
Match the compounds given in List -I wit...

Match the compounds given in List -I with their characteristic reactions given in List -II. Select the correct option.
`{:(,"List -I",,"List -II"),(,"Compounds",,"Reactions"),((a),CH_(3)CH_(2)CH_(2)CH_(2)NH_(2),(i),"alkaline hydroloysis"),((b),CH_(3)C-=CH,(ii),"with KOH (alcohol) and " CHCl_(3) " produces bad smell"),((c ),CH_(3)CH_(2)COOCH_(3),(iii),"given white ppt. with ammonical " AgNO_(3)),((d),CH_(3)CH(OH)CH_(3),(iv),"with Lucas reagent clodiness appears after 5 minutes"):}`

A

`{:("(a) (b) (c) (d)"),("(iii) (ii) (i) (iv)"):}`

B

`{:("(a) (b) (c) (d)"),("(ii) (iii) (i) (iv)"):}`

C

`{:("(a) (b) (c) (d)"),("(iv) (ii) (iii) (i)"):}`

D

`{:("(a) (b) (c) (d)"),("(ii) (i) (iv) (iii)"):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of matching the compounds from List-I with their characteristic reactions from List-II, we will analyze each compound and its corresponding reaction step by step. ### Step 1: Analyze Compound (a) CH₃CH₂CH₂CH₂NH₂ (Butane-1-amine) - Butane-1-amine is a primary amine. - When a primary amine reacts with KOH and chloroform, it produces isocyanide, which is known for its bad smell. - **Match:** (a) → (ii) "with KOH (alcohol) and CHCl₃ produces bad smell". ### Step 2: Analyze Compound (b) CH₃C≡CH (Propyne) - Propyne is an alkyne with a terminal hydrogen. - When it reacts with ammonical AgNO₃, it forms a white precipitate of silver acetylide. - **Match:** (b) → (iii) "given white ppt. with ammonical AgNO₃". ### Step 3: Analyze Compound (c) CH₃CH₂COOCH₃ (Methyl Propanoate) - Methyl propanoate is an ester. - Esters undergo alkaline hydrolysis to yield the corresponding carboxylic acid and alcohol. - **Match:** (c) → (i) "alkaline hydrolysis". ### Step 4: Analyze Compound (d) CH₃CH(OH)CH₃ (Propane-2-ol) - Propane-2-ol is a secondary alcohol. - When treated with Lucas reagent (HCl and ZnCl₂), it shows cloudiness after 5 minutes. - **Match:** (d) → (iv) "with Lucas reagent cloudiness appears after 5 minutes". ### Summary of Matches: - (a) → (ii) - (b) → (iii) - (c) → (i) - (d) → (iv) ### Final Answer: The correct matches are: - A-2, B-3, C-1, D-4.
Promotional Banner

Similar Questions

Explore conceptually related problems

State the products of the following reactions (i) CH_(3)-CH_(2)-CH_(2)-OCH_(3)+HIrarr (ii) (iii) (CH_(3))_(3)C-OCH_(3)+HI

Dipole moment of CH_(3)CH_(2)CH_(3)(I),CH_(3)CH_(2)OH(II) and CH_(3)CH_(2)F(III) is in order

Match the pairs of compounds (to be distinguished) given in Column-(I) with the appropriate reagents given in Column-II {:(,"Column-I",,"Column-II",),((A),CH_(3)-CH_(2)-CHO & "acetone",(P),"Ammoniacal" Cu_(2)Cl(2)"solution",),((B),CH_(3)-CH_(2)-CHO & "bezaldehyde",(Q),"Ammoniacal" AgNO_(3) "solution",),((C),CH_(3)-CH_(2)-C-=CH&CH_(3)-C-=C-CH_(3),(R),Br_(2) "in"C Cl_(4),),((D),CH_(3)-C-=CH &"propane",(S),"Fehling solution",),(,,(T),"Iodoform test",):}

Complete the follwing reaction equations : (i) (ii) CH_(3)CH_(2)CH=CH_(2)+HBrto

Name the functional groups present in the following compounds. (a) CH_(3)COCH_(2)CH_(2)CH_(2)CH_(3) , (b) CH_(3)CH_(2)CH_(2)COOH (c ) CH_(3)CH_(2)CH_(2)CH_(2)CHO , (d) CH_(3)CH_(2)OH

Predict the products of the following reactions : (i) CH_(3)-CH_(2)-CH_(2)-O-CH_(3)+HBrrarr (ii) (iii) (iv) (CH_(3))_(3)C-OC_(2)H_(5)+HIrarr

The reaction CH_(3)COCH_(3)underset((ii)KOH,"glycol")overset((i)NH_(2)-NH_(2))rarrCH_(3)CH_(2)CH_(3) is known as :

write the correct order of basic strength in gas phase is (I) CH_(3)-NH_(2) (II) (CH_(3))_(2)NH (III) (CH_(3))_(3)N (IV) NH_(3)

The correct order of basicities of the following compounds is - (I) , (II) CH_(3)CH_(2)NH_(2) : (III) (CH_(3))_(2)NH , (IV) CH_(3)-overset(O)overset(||)C-NH_(2))

Give the decreasing order of reactivity of the following alkyl halides in the Williamson's reaction. i. (CH_(3))_(3)C-CH_(2)Br ii. CICH_(2)CH=CH_(2) iii. (CICH_(2)CH_(2)CH_(3) iv. BrCH_(2)CH_(2)CH_(3)