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In which of the following compounds,nitr...

In which of the following compounds,nitrogen exhibits highest oxidation state?

A

`N_(3)H`

B

`NH_(2)OH`

C

`N_(2)H_(4)`

D

`NH_(3)`

Text Solution

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The correct Answer is:
To determine the compound in which nitrogen exhibits the highest oxidation state, we will calculate the oxidation state of nitrogen in each of the given compounds: N3H, NH2OH, N2H4, and NH3. ### Step 1: Calculate the oxidation state of nitrogen in N3H Let the oxidation state of nitrogen be \( X \). The compound N3H consists of: - 3 nitrogen atoms (3X) - 1 hydrogen atom (H has an oxidation state of +1) Setting up the equation for the neutral compound: \[ 3X + 1 = 0 \] Solving for \( X \): \[ 3X = -1 \] \[ X = -\frac{1}{3} \] ### Step 2: Calculate the oxidation state of nitrogen in NH2OH Let the oxidation state of nitrogen be \( X \). The compound NH2OH consists of: - 1 nitrogen atom (X) - 2 hydrogen atoms (2 × +1) - 1 oxygen atom (-2) Setting up the equation: \[ X + 2 + (-2) = 0 \] Solving for \( X \): \[ X + 0 = 0 \] \[ X = -1 \] ### Step 3: Calculate the oxidation state of nitrogen in N2H4 Let the oxidation state of nitrogen be \( X \). The compound N2H4 consists of: - 2 nitrogen atoms (2X) - 4 hydrogen atoms (4 × +1) Setting up the equation: \[ 2X + 4 = 0 \] Solving for \( X \): \[ 2X = -4 \] \[ X = -2 \] ### Step 4: Calculate the oxidation state of nitrogen in NH3 Let the oxidation state of nitrogen be \( X \). The compound NH3 consists of: - 1 nitrogen atom (X) - 3 hydrogen atoms (3 × +1) Setting up the equation: \[ X + 3 = 0 \] Solving for \( X \): \[ X = -3 \] ### Summary of Oxidation States - In N3H: \( -\frac{1}{3} \) (approximately -0.33) - In NH2OH: \( -1 \) - In N2H4: \( -2 \) - In NH3: \( -3 \) ### Conclusion The highest oxidation state of nitrogen among the given compounds is in **N3H**, where nitrogen has an oxidation state of \( -\frac{1}{3} \).

To determine the compound in which nitrogen exhibits the highest oxidation state, we will calculate the oxidation state of nitrogen in each of the given compounds: N3H, NH2OH, N2H4, and NH3. ### Step 1: Calculate the oxidation state of nitrogen in N3H Let the oxidation state of nitrogen be \( X \). The compound N3H consists of: - 3 nitrogen atoms (3X) - 1 hydrogen atom (H has an oxidation state of +1) ...
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