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The ease of adsorption of the hydrated a...

The ease of adsorption of the hydrated alkali metal ions on ion-exchange resins follows the order:
(a)`K^(+) lt Na^(+) lt Rb^(+) lt Li^(+)`
(b)`Na^(+) lt Li^(+) lt K^(+) lt Rb^(+)`
(c)`Li^(+) lt K^(+) lt Na^(+) lt Rb^(+)`
(d)`Rb^(+) lt K^(+) lt Na^(+) lt Li^(+)`

A

`K^(+) lt Na^(+) lt Rb^(+) lt Li^(+)`

B

`Na^(+) lt Li^(+) lt K^(+) lt Rb^(+)`

C

`Li^(+) lt K^(+) lt Na^(+) lt Rb^(+)`

D

`Rb^(+) lt K^(+) lt Na^(+) lt Li^(+)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the ease of adsorption of hydrated alkali metal ions on ion-exchange resins, we need to analyze the factors that influence this process. ### Step-by-Step Solution: 1. **Understanding Ion Size**: The ease of adsorption of ions on ion-exchange resins is primarily influenced by the size of the ions. Smaller ions tend to be adsorbed more easily than larger ions. 2. **Trends in Alkali Metal Ions**: Alkali metal ions (Li⁺, Na⁺, K⁺, Rb⁺) increase in size as we move down the group in the periodic table. Therefore, Li⁺ is the smallest, followed by Na⁺, K⁺, and Rb⁺, which is the largest. 3. **Effect of Size on Adsorption**: As the size of the ion increases, the ease of adsorption decreases. This means that the smaller the ion, the easier it is for it to be adsorbed onto the ion-exchange resin. 4. **Order of Ease of Adsorption**: Based on the size of the ions, we can establish the order of ease of adsorption: - Li⁺ (smallest) > Na⁺ > K⁺ > Rb⁺ (largest) 5. **Conclusion**: Therefore, the correct order of ease of adsorption of the hydrated alkali metal ions on ion-exchange resins is: - **Li⁺ > Na⁺ > K⁺ > Rb⁺** 6. **Selecting the Correct Option**: The correct option that reflects this order is: - (d) Rb⁺ < K⁺ < Na⁺ < Li⁺ ### Final Answer: The correct answer is (d) Rb⁺ < K⁺ < Na⁺ < Li⁺.

To solve the question regarding the ease of adsorption of hydrated alkali metal ions on ion-exchange resins, we need to analyze the factors that influence this process. ### Step-by-Step Solution: 1. **Understanding Ion Size**: The ease of adsorption of ions on ion-exchange resins is primarily influenced by the size of the ions. Smaller ions tend to be adsorbed more easily than larger ions. 2. **Trends in Alkali Metal Ions**: Alkali metal ions (Li⁺, Na⁺, K⁺, Rb⁺) increase in size as we move down the group in the periodic table. Therefore, Li⁺ is the smallest, followed by Na⁺, K⁺, and Rb⁺, which is the largest. ...
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