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XeF2 is isostructural with...

`XeF_2` is isostructural with

A

`TeF_(2)`

B

`ICl_(2)^(-)`

C

`SbCl_(3)`

D

`BaCl_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound is isostructural with \( \text{XeF}_2 \), we need to analyze the structure of \( \text{XeF}_2 \) and compare it with the given options: \( \text{TeF}_2 \), \( \text{YCl}_2^- \), \( \text{SbCl}_3 \), and \( \text{BaCl}_2 \). ### Step-by-Step Solution: 1. **Identify the Structure of \( \text{XeF}_2 \)**: - \( \text{XeF}_2 \) has a central xenon (Xe) atom surrounded by two fluorine (F) atoms. - The molecular geometry of \( \text{XeF}_2 \) is linear due to the presence of three lone pairs of electrons on the xenon atom. 2. **Determine the Valence Electrons**: - Xenon (Xe) has 8 valence electrons. - Each fluorine (F) contributes 1 electron, but we focus on the central atom for isostructural comparison. 3. **Analyze Given Compounds**: - **\( \text{TeF}_2 \)**: Tellurium (Te) has 6 valence electrons. With 2 fluorine atoms, it does not match the electron count of xenon. - **\( \text{YCl}_2^- \)**: Yttrium (Y) has 3 valence electrons. With 2 chlorine atoms and a negative charge, it totals 8 electrons (3 from Y + 2 from each Cl + 1 from the charge). The structure is linear with 3 lone pairs on Y, similar to \( \text{XeF}_2 \). - **\( \text{SbCl}_3 \)**: Antimony (Sb) has 5 valence electrons. With 3 chlorine atoms, it totals 8 electrons, but the geometry is trigonal pyramidal, not linear. - **\( \text{BaCl}_2 \)**: Barium (Ba) has 2 valence electrons. With 2 chlorine atoms, it totals 4 electrons, which does not match. 4. **Conclusion**: - The only compound that has the same number of valence electrons and a linear structure is \( \text{YCl}_2^- \). ### Final Answer: The compound that is isostructural with \( \text{XeF}_2 \) is \( \text{YCl}_2^- \).

To determine which compound is isostructural with \( \text{XeF}_2 \), we need to analyze the structure of \( \text{XeF}_2 \) and compare it with the given options: \( \text{TeF}_2 \), \( \text{YCl}_2^- \), \( \text{SbCl}_3 \), and \( \text{BaCl}_2 \). ### Step-by-Step Solution: 1. **Identify the Structure of \( \text{XeF}_2 \)**: - \( \text{XeF}_2 \) has a central xenon (Xe) atom surrounded by two fluorine (F) atoms. - The molecular geometry of \( \text{XeF}_2 \) is linear due to the presence of three lone pairs of electrons on the xenon atom. ...
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