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The major organic product in the reactio...

The major organic product in the reaction
`CH_(3)-O-CH(CH_(3))_(2)+HIrarr` product is

A

CH3OH + (CH3)2CHI

B

`ICH_(2)OCH(CH_(3))_(2)`

C

`CH_(3)Ounderset(I)underset(|)(C)(CH_(3))_(2)`

D

`CH_(3)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To find the major organic product of the reaction between the ether \( CH_3-O-CH(CH_3)_2 \) and hydrogen iodide (HI), we can follow these steps: ### Step 1: Identify the Reactants The reactant is an ether, specifically \( CH_3-O-CH(CH_3)_2 \). It consists of a methyl group (\( CH_3 \)) and an isopropyl group (\( CH(CH_3)_2 \)) connected by an oxygen atom. ### Step 2: Mechanism of Reaction The reaction proceeds via an SN1 mechanism. This is because the ether can form a stable secondary carbocation when it reacts with HI. The oxygen atom in the ether has lone pairs that can interact with the hydrogen from HI, leading to the formation of a carbocation. ### Step 3: Protonation of the Ether The oxygen atom in the ether will protonate by accepting a hydrogen ion (H⁺) from HI. This results in the formation of an oxonium ion: \[ CH_3-OH^+-CH(CH_3)_2 \] ### Step 4: Carbocation Formation Once the ether is protonated, the bond between the oxygen and the isopropyl group can break, leading to the formation of a secondary carbocation: \[ CH_3^+-C(CH_3)_2 \] ### Step 5: Nucleophilic Attack Now, the iodide ion (I⁻) from HI can attack the carbocation. Since the carbocation is secondary, it is relatively stable, and the iodide ion will preferentially attack this positive charge. ### Step 6: Formation of the Product The final product formed after the nucleophilic attack will be: \[ CH_3-CH(CH_3)_2-I \] This product is 1-iodo-2-methylpropane. ### Final Answer The major organic product of the reaction is: \[ CH_3-CH(CH_3)_2-I \]

To find the major organic product of the reaction between the ether \( CH_3-O-CH(CH_3)_2 \) and hydrogen iodide (HI), we can follow these steps: ### Step 1: Identify the Reactants The reactant is an ether, specifically \( CH_3-O-CH(CH_3)_2 \). It consists of a methyl group (\( CH_3 \)) and an isopropyl group (\( CH(CH_3)_2 \)) connected by an oxygen atom. ### Step 2: Mechanism of Reaction The reaction proceeds via an SN1 mechanism. This is because the ether can form a stable secondary carbocation when it reacts with HI. The oxygen atom in the ether has lone pairs that can interact with the hydrogen from HI, leading to the formation of a carbocation. ...
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