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The correct order regarding the electron...

The correct order regarding the electronegativity of hybrid orbitals of carbon is:-

A

`sp gt sp^(2) lt sp^(3)`

B

`sp gt sp^(2) gt sp^(3)`

C

`sp lt sp^(2) gt sp^(3)`

D

`sp lt sp^(2) lt sp^(3) `

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct order regarding the electronegativity of hybrid orbitals of carbon (sp, sp², sp³), we can follow these steps: ### Step 1: Understand Hybridization Hybridization is the mixing of atomic orbitals to form new hybrid orbitals. For carbon, the types of hybridization are sp, sp², and sp³. ### Step 2: Identify the Percent s Character The percent s character in each type of hybrid orbital can be calculated as follows: - **sp Hybridization**: - In sp hybridization, there is 1 s orbital and 1 p orbital. - Percent s character = (Number of s orbitals / Total number of orbitals) × 100 - Percent s character = (1 / 2) × 100 = 50% - **sp² Hybridization**: - In sp² hybridization, there is 1 s orbital and 2 p orbitals. - Percent s character = (1 / 3) × 100 = 33.33% - **sp³ Hybridization**: - In sp³ hybridization, there is 1 s orbital and 3 p orbitals. - Percent s character = (1 / 4) × 100 = 25% ### Step 3: Relate Percent s Character to Electronegativity Electronegativity is directly proportional to the percent s character in hybrid orbitals. This means that as the percent s character increases, the electronegativity also increases. ### Step 4: Compare the Percent s Characters From the calculations: - sp hybridization: 50% s character - sp² hybridization: 33.33% s character - sp³ hybridization: 25% s character ### Step 5: Determine the Order of Electronegativity Based on the percent s character, we can conclude: - sp > sp² > sp³ ### Final Answer The correct order regarding the electronegativity of hybrid orbitals of carbon is: **sp > sp² > sp³**
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