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Anisole on cleavage with HI gives:...

Anisole on cleavage with HI gives:

A

B

C

D

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Anisole on reaction with HI gives phenol and CH_(3)-I as the main products and not iodobenzene and CH_(3)OH. Assign reasons.

(A) tert-Butyl methyl ether on cleavage with HI at 373K gives tert-butyl iodide and methanol. (R ) The reaction occurs by S_(N^(2)) mechanism.

Knowledge Check

  • Phenyl methyl ether (on anisole) reacts with HI to give phenol and methyl iodide and not iodobenzene and methyl alcohol. Justify .

    A
    `I^-` ion prefers to combie with the smaller group in order to minimise steric hindrance group in order to minimise steric hindrance
    B
    `I^-` ion is not ractive towards benzne
    C
    phenol is formed as a result of hydrolyis of iodobenzene
    D
    mehtyl alcohol fromed durin reaction racts wit `I^-` to from methyl iodile .

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