Home
Class 12
CHEMISTRY
How can Kohlrausch's law of independent ...

How can Kohlrausch's law of independent migration can be applied for calculating the degree of dissociation `(alpha)` of weak electrolytes ?

Text Solution

Verified by Experts

The `wedge_(m)^(oo)` values can also be used to calculate the degree of dissociation `(alpha_(c ))` and also the dissociation constants of weak acids and weak bases. According to Arrhenius :
`alpha_(c )=(wedge_(m)^( c))/(wedge_(m)^(oo))`
where `wedge_(m)^( c)` as is the molar conductivity of the electrolyte at concentration c and `alpha_(c )` is its degree of dissociation at concentration c.
Knowing the degree of dissociation, `alpha`, the dissociation constant `K_(c )` of a weak electrolyte can be calculated by using the relation:
`K_(c )=(c alpha^(2))/((1-alpha))`
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    ICSE|Exercise Follow up Problems|48 Videos
  • ELECTROCHEMISTRY

    ICSE|Exercise EXERCISE (PART-I Objective Questions)|28 Videos
  • DISTINCTION BETWEEN PAIRS OF COMPOUNDS

    ICSE|Exercise QUESTIONS |155 Videos
  • GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

    ICSE|Exercise EXERCISE (PART-I ( OBJECTIVE QUESTIONS )) (Fill in the blanks)|60 Videos

Similar Questions

Explore conceptually related problems

Mendel's law of independent assortment can be demonstrated by

State Kohlrausch's Law for the independent migration of ions. Mention the applications of the Law.

Law of independent assortment can be explained with the help of

If degree of ionization (alpha) of a weak electrolyte AB is very less then alpha is :

Law of mass action can not be applied to

STATEMENT 1 Using koihlrausch's law of independent migration of ions it is possible to calculate wedge^(@) for anyelectrolyte form the lambda^(@) of individual ions STATEMENT 2 : Limiting molar molar conductivity of na electrolyte can be repersented as the sum of hte individual contribution of the anion and cation of hte electrolyte STATEMENT 3: When concentration appraches zero molar conductivity reaches the lowest limit

For the weak electrolyte , their degree of dissociation increase

HA is a weak acid. The pH of 0.1 M HA solution is 2. What is the degree of dissociation (alpha) of HA ?

Kolbe's electrolytic method can be applied on

How Nernst equation can be applied in the calculation of equilibrium constant of any cell reaction ?

ICSE-ELECTROCHEMISTRY-ISC EXAMINATION QUESTIONS (PART-II Numerical Problems)
  1. How can Kohlrausch's law of independent migration can be applied for ...

    Text Solution

    |

  2. A cell is constructed by dipping a zinc rod in 0.1 M zinc nitrate solu...

    Text Solution

    |

  3. For the cell : Zn"|"Zn^(2+) (a=1)"||"Cu^(2+) (a=1)"|"Cu Given that ...

    Text Solution

    |

  4. Calculate the equivalent conductivity of 1M H(2)SO(4), whose specific...

    Text Solution

    |

  5. A current of 10 A is passed for 80 min and 27 seconds through a cell ...

    Text Solution

    |

  6. Calculate E("cell") at 25^(@)C for the reaction : Zn+Cu^(2+) (0.2...

    Text Solution

    |

  7. A 0.05 M NaOH solution offered a resistance of 31.6 ohms in a conduct...

    Text Solution

    |

  8. For the following cell, calculate the emf: Al//Al^(3+) (0.01 M)"||"...

    Text Solution

    |

  9. A solution of 0.1 N KCl offers a resistance of 245 ohms. Calculate th...

    Text Solution

    |

  10. How many electrons will flow when a current of 5 amperes is passed thr...

    Text Solution

    |

  11. Consider the reaction 2Ag^(+) +Cd to 2Ag to 2Ag +Cd^(2+). The stan...

    Text Solution

    |

  12. Calculate the maximum work that can be obtained from the given electr...

    Text Solution

    |

  13. Calculate the value of E("cell") at 298 K for the following cell: ...

    Text Solution

    |

  14. 0*05 " M " NaOH solution offered a resistance of 31*6 ohm in a conduct...

    Text Solution

    |

  15. 0*3605 g of a metal is deposited on the electrode by passing 1*2 amper...

    Text Solution

    |

  16. How many hours does it take to reduce 3 moles of Fe^(3+) to Fe^(2+) wi...

    Text Solution

    |

  17. Calculate the emf of the following cell reaction at 298 K: Mg(s) +C...

    Text Solution

    |

  18. The specific conductance of a 0.01 M solution of acetic acid at 298 K...

    Text Solution

    |

  19. Calculate the number of coulombs required to deposit 5.4g of Al when ...

    Text Solution

    |

  20. A 0.05 M NH OH solution offers the resistance of 50 ohms to a conduct...

    Text Solution

    |