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For the chemical equilibrium PCl(5)(g)...

For the chemical equilibrium
`PCl_(5)(g) hArr PCl_(3)(g) +Cl_(2) (g) " at " 298K, K_(c )=1.8xx10^(-7)`.
Calculate `Delta_(r )G^(Theta)` for the forward reaction `R=8.31JK^(-1)"mol"^(-1)`

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To calculate \(\Delta_r G^\Theta\) for the forward reaction of the equilibrium \(PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)\) at 298 K with \(K_c = 1.8 \times 10^{-7}\), we can use the following formula: \[ \Delta_r G^\Theta = -2.303 \cdot R \cdot T \cdot \log K_c \] where: - \(R\) is the universal gas constant, given as \(8.31 \, \text{J K}^{-1} \text{mol}^{-1}\) - \(T\) is the temperature in Kelvin, given as \(298 \, \text{K}\) - \(K_c\) is the equilibrium constant, given as \(1.8 \times 10^{-7}\) ### Step-by-Step Solution: 1. **Identify the values**: - \(R = 8.31 \, \text{J K}^{-1} \text{mol}^{-1}\) - \(T = 298 \, \text{K}\) - \(K_c = 1.8 \times 10^{-7}\) 2. **Calculate \(\log K_c\)**: \[ \log K_c = \log(1.8 \times 10^{-7}) \] Using a calculator or logarithm table: \[ \log(1.8) \approx 0.2553 \quad \text{and} \quad \log(10^{-7}) = -7 \] Therefore: \[ \log K_c = 0.2553 - 7 = -6.7447 \] 3. **Substitute the values into the equation**: \[ \Delta_r G^\Theta = -2.303 \cdot 8.31 \cdot 298 \cdot (-6.7447) \] 4. **Calculate the product**: - First calculate \(2.303 \cdot 8.31 \cdot 298\): \[ 2.303 \cdot 8.31 \cdot 298 \approx 5730.86 \] 5. **Calculate \(\Delta_r G^\Theta\)**: \[ \Delta_r G^\Theta = -5730.86 \cdot (-6.7447) \approx 38516.52 \, \text{J} \] Converting to kilojoules: \[ \Delta_r G^\Theta \approx 38.516 \, \text{kJ} \] ### Final Answer: \[ \Delta_r G^\Theta \approx 38.52 \, \text{kJ} \]

To calculate \(\Delta_r G^\Theta\) for the forward reaction of the equilibrium \(PCl_5(g) \rightleftharpoons PCl_3(g) + Cl_2(g)\) at 298 K with \(K_c = 1.8 \times 10^{-7}\), we can use the following formula: \[ \Delta_r G^\Theta = -2.303 \cdot R \cdot T \cdot \log K_c \] where: - \(R\) is the universal gas constant, given as \(8.31 \, \text{J K}^{-1} \text{mol}^{-1}\) ...
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