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The molar conductivity of NH(4)Cl at inf...

The molar conductivity of `NH_(4)Cl` at infinite dilution is 149.7`"ohm"^(-)cm^(2)"mol"^(-1)` and ionic conductances of hydroxyl ions and chloride ions are 198 and 76.3 respectively. Calculate the molar conductivity of `NH_(4)OH` at infinite dilution.

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To calculate the molar conductivity of \( NH_4OH \) at infinite dilution, we can use the relationship between the molar conductivities of the involved species. The relevant equation is: \[ \Lambda_{m}(NH_4OH) = \Lambda_{m}(NH_4Cl) + \Lambda_{m}(OH^-) - \Lambda_{m}(Cl^-) \] Where: - \( \Lambda_{m}(NH_4OH) \) is the molar conductivity of ammonium hydroxide at infinite dilution. - \( \Lambda_{m}(NH_4Cl) \) is the molar conductivity of ammonium chloride at infinite dilution, which is given as \( 149.7 \, \Omega^{-1} \, cm^2 \, mol^{-1} \). - \( \Lambda_{m}(OH^-) \) is the ionic conductivity of hydroxyl ions, given as \( 198 \, \Omega^{-1} \, cm^2 \, mol^{-1} \). - \( \Lambda_{m}(Cl^-) \) is the ionic conductivity of chloride ions, given as \( 76.3 \, \Omega^{-1} \, cm^2 \, mol^{-1} \). Now, we can substitute the values into the equation: 1. Start with the known values: - \( \Lambda_{m}(NH_4Cl) = 149.7 \, \Omega^{-1} \, cm^2 \, mol^{-1} \) - \( \Lambda_{m}(OH^-) = 198 \, \Omega^{-1} \, cm^2 \, mol^{-1} \) - \( \Lambda_{m}(Cl^-) = 76.3 \, \Omega^{-1} \, cm^2 \, mol^{-1} \) 2. Substitute these values into the equation: \[ \Lambda_{m}(NH_4OH) = 149.7 + 198 - 76.3 \] 3. Perform the calculations step by step: - First, add \( 149.7 + 198 \): \[ 149.7 + 198 = 347.7 \] - Then subtract \( 76.3 \): \[ 347.7 - 76.3 = 271.4 \] 4. Therefore, the molar conductivity of \( NH_4OH \) at infinite dilution is: \[ \Lambda_{m}(NH_4OH) = 271.4 \, \Omega^{-1} \, cm^2 \, mol^{-1} \] ### Final Answer: The molar conductivity of \( NH_4OH \) at infinite dilution is \( 271.4 \, \Omega^{-1} \, cm^2 \, mol^{-1} \).

To calculate the molar conductivity of \( NH_4OH \) at infinite dilution, we can use the relationship between the molar conductivities of the involved species. The relevant equation is: \[ \Lambda_{m}(NH_4OH) = \Lambda_{m}(NH_4Cl) + \Lambda_{m}(OH^-) - \Lambda_{m}(Cl^-) \] Where: - \( \Lambda_{m}(NH_4OH) \) is the molar conductivity of ammonium hydroxide at infinite dilution. ...
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