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Why is equilibrium constant K related to...

Why is equilibrium constant K related to only `E_("cell")^(Theta)` and not `E_("cell")`?

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To understand why the equilibrium constant \( K \) is related only to \( E_{\text{cell}}^{\Theta} \) (the standard cell potential) and not to \( E_{\text{cell}} \) (the actual cell potential), we can follow these steps: ### Step 1: Understand the Nernst Equation The Nernst equation is given by: \[ E_{\text{cell}} = E_{\text{cell}}^{\Theta} - \frac{RT}{nF} \ln Q \] where: ...
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What does the negative value of E_("cell")^(Theta) indicate?

For a spontaneous reaction, DeltaG, equilibrium constant (K) and E_(cell)^(@) will be respectively:

The following chemical reaction is occurring in an electrochemical cell, Mg(s) +2Ag^(+) (0.0001 M) to Mg^(2+) (0.10 M) +2Ag(s) Mg^(2+) //Mg = -2.36V, Ag^(+)//Ag=0.81V For this cell calculate/write (a) (i) E^(Theta) value for the electrode 2 Ag^(+)//2Ag . (ii) Standard cell potential E_("cell")^(Theta) (b) Cell potential (E )_("cell") (c ) (i) Symbolic representation of the above cell. (ii) Will the above cell reaction be spontaneous ?

The change in Gibbs free energy of the system along provides a criterion for the spontaneity of a process at constant temperature and pressure. A change in the free energy of a sytem at constant temperature and pressure will be: DeltaG_("system") = DeltaH_("system") - T DeltaS_("system") For a spontaneous reaction DeltaG , equilibrium constant K and E_("cell")^(0) will be respectively:

The value of equilibrium constant for a feasible cell reaction is :

The logarithm of the equilibriium constant of the cell reaction corresponding to the cell X(s)|x^(2+)(aq)||Y^(+)(aq)|Y(s) with standard cell potential E_(cell)^(@)=1.2V given by

Consider the following reaction, Zn(s)+Cu^(2+) (0.1 M) rarr Zn^(2+) (1 M)+Cu(s) above reaction, taking place in a cell, E_("cell")^(@) is 1.10 V. E_("cell") for the cell will be (2.303 (RT)/(F)=0.0591)

In a cell that utilises the reaction. Zn(s) +2H^(+)(aq) rarr Zn^(2+) (aq) +H_(2)(s) addition of H_(2)SO_(4) to cathode compartement, will: (1) increase the E_(Cell) and shift equilibrium to the right (2) lower the E_(cell) and shift equilibrium to the right (3) lower the E_(cell) and shift equilibrium to the left (4) increase the E_(cell) and shift equilibrium to the left

For A+BhArrC+D , the equilibrium constant is K_(1) and for C+DhArrA+B , the equilibrium constant is K_(2) . The correct relation between K_(1) and K_(2) is

In which of the following cell(s): E_("cell")=E_("cell")^(@) ?

ICSE-ELECTROCHEMISTRY-EXERCISE (PART-II Descriptive Questions)
  1. Write Nernst equation for the reaction: (i) 2Cr(s) +3Cd^(2+)(aq) to...

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  2. Discuss the relation between free energy and EMF.

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  3. Why is equilibrium constant K related to only E("cell")^(Theta) and n...

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  4. What is the relationship between specific conductance and equivalent c...

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  5. The unit of equivalent conductance is :

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  6. What is meant by cell constant ?

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  7. Express mathematically relationship among the resistance (R ), specifi...

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  8. Define the term molar conductivity.

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  9. How is the unit of molar conductivity arrived ?

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  10. State Kohlrausch law for electrical conductance of an electrolyte at ...

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  11. What is the effect of decreasing concentration on the molar conductiv...

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  12. Express mathematically the relationship among the degree of dissociat...

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  13. Write mathematical expression for Kohlrausch law.

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  14. Write Debye-Huckel-Onsager equation. What do different symbols signif...

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  15. How does electrical conductivity of semiconductors vary with temperat...

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  16. During electrolysis :

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  17. State Faraday's first law of electrolysis.

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  18. State Faraday's second law of electrolysis. How is the law helpful in ...

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  19. What is meant by electrochemical equivalent of a substance?

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  20. What is meant by Faraday's constant?

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