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The unit of equivalent conductance is :...

The unit of equivalent conductance is :

A

`"ohm"^(-1)cm^(2)"equiv"^(-1)`

B

`"ohm"^(-1)cm^(2)g^(-1)`

C

`"ohm cm"^(2)"equiv"^(-1)`

D

`"ohm"^(-1)"mol"^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the unit of equivalent conductance, we can follow these steps: ### Step 1: Understand Equivalent Conductance Equivalent conductance (Λ) is defined as the conductance of a solution containing one gram equivalent of an electrolyte in one cubic meter (m³) of solution. ### Step 2: Know the Formula for Equivalent Conductance The formula for equivalent conductance is given by: \[ \Lambda = \frac{\text{Conductivity} (\kappa)}{\text{Normality} (N)} \] ### Step 3: Identify Units of Conductivity The unit of conductivity (κ) is the reciprocal of resistivity. Therefore, the unit of conductivity is: \[ \text{Unit of Conductivity} = \frac{1}{\text{Ohm}} \cdot \text{cm}^{-1} = \text{Ohm}^{-1} \cdot \text{cm}^{-1} \] ### Step 4: Identify Units of Normality Normality (N) is defined as the number of equivalents of solute per liter of solution. The unit of normality is: \[ \text{Unit of Normality} = \text{equivalents} \cdot \text{L}^{-1} = \text{equivalents} \cdot \text{cm}^{-3} \] ### Step 5: Substitute Units into the Equivalent Conductance Formula Now, substituting the units of conductivity and normality into the formula for equivalent conductance: \[ \Lambda = \frac{\text{Ohm}^{-1} \cdot \text{cm}^{-1}}{\text{equivalents} \cdot \text{cm}^{-3}} \] ### Step 6: Simplify the Units When we simplify this expression, we get: \[ \Lambda = \text{Ohm}^{-1} \cdot \text{cm}^{-1} \cdot \frac{\text{cm}^{3}}{\text{equivalents}} = \frac{\text{cm}^{2}}{\text{Ohm} \cdot \text{equivalents}} \] ### Step 7: Final Unit of Equivalent Conductance Thus, the unit of equivalent conductance can be expressed as: \[ \text{Unit of Equivalent Conductance} = \frac{\text{cm}^2}{\text{Ohm} \cdot \text{equivalent}} = \text{per Ohm cm}^2 \text{ per equivalent} \] ### Conclusion The correct option for the unit of equivalent conductance is: **Per Ohm Centimetre Square Per Equivalent.**
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