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For the following cell, calculate the em...

For the following cell, calculate the emf:
`Al//Al^(3+) (0.01 M)"||" Fe^(2+) (0.02M)"|"Fe`
Given: `E_(Al^(3+)//Al)^(Theta) = -1.66V, E_(Fe^(2+)//Fe)^(Theta)= -0.44V`

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AI Generated Solution

To calculate the emf of the given electrochemical cell, we will follow these steps: ### Step 1: Identify the half-reactions and their standard electrode potentials. - The half-reaction for aluminum is: \[ \text{Al}^{3+} + 3e^- \rightarrow \text{Al} \quad E^\circ = -1.66 \, \text{V} \] - The half-reaction for iron is: ...
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For the following cell, Calculate the emf: Al/ Al^(3+) (0.01M)// Fe^(2+) (0.02M)/Fe Given: E^(@)Al^(+3) /Al=−1.86V, E^(@)Fe^(2+) /Fe =−0.54V.

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(a) State the relationship amongst cell constant of a cell , resistance of the solution in the cell and conductivity of the solution . How is molar conductivity of solute related to conductivity of its solution ? (b) A voltanic cell is set up at 25^(@)C with the following half-cells : Al|Al^(3+) (0.001M) and Ni|Ni^(2+) (0.50M) Calculate the cell voltage [ E_(Ni^(2+)|Ni)^(@) = -0.25V , E_(Al^(3+) |Al)^(@) = -1.66 V ]

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  12. Calculate the value of E("cell") at 298 K for the following cell: ...

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