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The ligand which is not chelating is :...

The ligand which is not chelating is :

A

EDTA

B

`C_2O_4^(2-)`

C

`CH_3COO^(-)`

D

`en`.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which ligand is not chelating, we need to understand the concept of chelation and the types of ligands. ### Step-by-Step Solution: 1. **Define Chelating Ligands**: - Chelating ligands are polydentate ligands that can bind to a central metal atom at multiple points, forming a ring structure. This property is known as chelation. 2. **Identify the Ligands Given**: - The ligands mentioned in the question are: - EDTA (Ethylenediaminetetraacetic acid) - C₂O₄²⁻ (Oxalate ion) - CH₃C(=O)O⁻ (Acetate ion) - Ethylene diamine (en) 3. **Classify Each Ligand**: - **EDTA**: This is a hexadentate ligand, meaning it has six donor atoms and can form multiple bonds with a metal ion, thus exhibiting chelation. - **C₂O₄²⁻ (Oxalate)**: This is a bidentate ligand, having two donor atoms that can bind to a metal ion, also exhibiting chelation. - **CH₃C(=O)O⁻ (Acetate)**: This is a monodentate ligand, meaning it has only one donor atom and can only bind to a metal ion at one point. Therefore, it does not exhibit chelation. - **Ethylene diamine (en)**: This is a bidentate ligand, having two donor atoms, and can also exhibit chelation. 4. **Conclusion**: - Among the ligands listed, the acetate ion (CH₃C(=O)O⁻) is the only ligand that is not chelating because it is monodentate and can only form one bond with a metal ion. ### Final Answer: The ligand which is not chelating is **CH₃C(=O)O⁻ (Acetate ion)**.

To determine which ligand is not chelating, we need to understand the concept of chelation and the types of ligands. ### Step-by-Step Solution: 1. **Define Chelating Ligands**: - Chelating ligands are polydentate ligands that can bind to a central metal atom at multiple points, forming a ring structure. This property is known as chelation. 2. **Identify the Ligands Given**: ...
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Knowledge Check

  • Which of the following ligands will not show chelation ?

    A
    EDTA
    B
    DMG
    C
    Ethane-1, 2- diamine
    D
    `SCN^(-)`
  • A chelating agent has two or more than two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent?

    A
    Thiosulphato
    B
    Oxalato
    C
    Glycinato
    D
    Ethane-1 , 2- diamine
  • Similar Questions

    Explore conceptually related problems

    Which of the following is not chelating agent (a) Thiosulphate (b) Oxalato (c ) Glycinato (d) Ethylene diamine .

    Consider the two complexation equilibria in aqueous solution, between the cobalt (II) ion Co^(2+) (aq) and ethylenediamine (en) on the one hand and ammonia NH_(3) on the other. [Co(H_(2)O)_(6)]^(2+)+6NH_(3)hArr[Co(NH_(3))_(6)]^(2+)+6H_(2)O ...(1) [Co(H_(2)O_(6))]^(2+)+3enhArr[Co(en)_(3)]^(2+)+6H_(2)O ..(2) Electronicaly, the ammonia and en ligands are very similar, since both bond through N and since the liwis base strengths of their nitrogen atoms are similar. This means that DeltaH^(@) must be very similar for the two reactions, since six Co-N bonds are formed in each case. Interestingly however, the equilibrium constant is 100,000 times larger for the second reaction than it is for the first. This is the so called chelate effect: "the enhanced affinity of chelating ligands for a metal ion compared to similar non-chelating (monodentate) ligands for the same metal". The chelate effect is entropy-driven. Q. Which of the following can be classified as a chelating ligand?

    Give the number of ligand(s) which is//are non-classical ligand CO, NO, C_(2)H-(4),C_(3)H_(5) Θ , H^(Θ) .

    Which of the following represents chelating ligand ?

    Which can form chelates?

    Which is not a bidentate ligand?