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Arrange the following in the decreasing ...

Arrange the following in the decreasing order of their boiling points:
(i) n-Butyl chloride (ii) Isobutyl chloride (iii) ter-Butyl chloride.

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To arrange n-Butyl chloride, Isobutyl chloride, and ter-Butyl chloride in decreasing order of their boiling points, we need to analyze the structures and the effects of branching on boiling points. Here’s a step-by-step solution: ### Step 1: Identify the Structures 1. **n-Butyl chloride (C4H9Cl)**: This has a straight-chain structure: CH3-CH2-CH2-CH2-Cl. 2. **Isobutyl chloride (C4H9Cl)**: This has a branched structure: CH3-CH(CH3)-CH2-Cl. 3. **ter-Butyl chloride (C4H9Cl)**: This has a more branched structure: (CH3)3C-Cl. ### Step 2: Understand the Effect of Branching on Boiling Points ...
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