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(a) Explain why cleavage of phenyl ether...

(a) Explain why cleavage of phenyl ethers with HBr always produces phenol and alkyl bromides and not bromobenzene and alkanols.
(b) Give reasons for the following:
(i) The dipole moment of diethyl ether (1.18D) is lower than that of water (1.84D).
(ii) The C-O-C bond angle in ethers is higher than H-O-H angle in water though oxygen is sp3 hybridized in both the cases.
(iii) Dimethyl ether is completely miscible with water but diethyl ether is soluble in water to a small extent.

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ICSE-ALCOHOLS, PHENOLS AND ETHERS -EXERCISE (PART-II Descriptive Questions) (LONG ANSWER QUESTIONS)
  1. What are monohydric alcohols and how are they classified? Give any th...

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  2. How is methanol obtained from methyl bromide ? How would you convert ...

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  3. What is fermentation ? Describe the manufacture of ethyl alcohol from...

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  4. How is ethyl alcohol prepared ? Give its important properties and use...

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  5. Explain the terms: (i) Grignard reagent (ii) Dow process (iii)...

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  6. (a) How do primary, secondary and tertiary alcohols differ in their b...

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  7. Name one reagent which is used for the distinction of primary, second...

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  8. (a) Write the industrial uses of methyl alcohol, ethyl alcohol and ph...

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  9. (a) Give one method each for the industrial preparation of: (i) et...

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  10. Account for the following: (i) In reaction involving cleavage of c...

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  11. (a) Write chemical equations and reaction conditions for the conversi...

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  12. Complete the following reactions : (i) (CH(3))(2)CO overset(LiAlH(4...

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  13. (a) Give the equations of the following reactions: (i) Oxidation of...

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  14. What are ethers? How are they classified ? Give two methods by which ...

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  15. (a) Discuss Williamson method to prepare ethers. Give the limitations...

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  16. Phenyl methyl ether reacts with HI to give phenol and methyl iodide a...

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  17. Write the names of reagents and equations for the preparation of the f...

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  18. (a) Explain why cleavage of phenyl ethers with HBr always produces ph...

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  19. How can you prepare diethyl ether in the laboratory? State its four ph...

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  20. Give the equations for the following reactions in case of anisole: ...

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