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The molecular shapes of SF4, CF4 and XeF...

The molecular shapes of `SF_4, CF_4 and XeF_4` are

A

different with 1, 0 and 2 lone pairs of electrons on the central atom, respectively

B

different with 0, 1 and 2 lone pairs of electrons on the central atom, respectively

C

the same with 1, 1 and 1 lone pair of electrons on the central atom, respectively

D

the same with 2,0 and 1 lone pairs of electrons on the central atom, respectively.

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The correct Answer is:
To determine the molecular shapes of SF₄, CF₄, and XeF₄, we will follow these steps: ### Step 1: Determine the Steric Number for SF₄ 1. **Identify the central atom and its valence electrons**: Sulfur (S) has 6 valence electrons. 2. **Count the number of monovalent atoms attached**: There are 4 fluorine (F) atoms attached to sulfur. 3. **Calculate the steric number** using the formula: \[ \text{Steric Number} = \frac{(V + M)}{2} \] where \(V\) is the number of valence electrons and \(M\) is the number of monovalent atoms. \[ \text{Steric Number} = \frac{(6 + 4)}{2} = \frac{10}{2} = 5 \] ### Step 2: Determine the Hybridization and Shape for SF₄ 1. **Identify the hybridization**: With a steric number of 5, the hybridization is sp³d. 2. **Determine the number of lone pairs**: Since there are 4 bond pairs (from the 4 F atoms) and 1 lone pair, the molecular shape is **seesaw**. ### Step 3: Determine the Steric Number for CF₄ 1. **Identify the central atom and its valence electrons**: Carbon (C) has 4 valence electrons. 2. **Count the number of monovalent atoms attached**: There are 4 fluorine (F) atoms attached to carbon. 3. **Calculate the steric number**: \[ \text{Steric Number} = \frac{(4 + 4)}{2} = \frac{8}{2} = 4 \] ### Step 4: Determine the Hybridization and Shape for CF₄ 1. **Identify the hybridization**: With a steric number of 4, the hybridization is sp³. 2. **Determine the number of lone pairs**: There are 4 bond pairs and 0 lone pairs, so the molecular shape is **tetrahedral**. ### Step 5: Determine the Steric Number for XeF₄ 1. **Identify the central atom and its valence electrons**: Xenon (Xe) has 8 valence electrons. 2. **Count the number of monovalent atoms attached**: There are 4 fluorine (F) atoms attached to xenon. 3. **Calculate the steric number**: \[ \text{Steric Number} = \frac{(8 + 4)}{2} = \frac{12}{2} = 6 \] ### Step 6: Determine the Hybridization and Shape for XeF₄ 1. **Identify the hybridization**: With a steric number of 6, the hybridization is sp³d². 2. **Determine the number of lone pairs**: There are 4 bond pairs and 2 lone pairs, so the molecular shape is **square planar**. ### Summary of Molecular Shapes - **SF₄**: Seesaw (1 lone pair) - **CF₄**: Tetrahedral (0 lone pairs) - **XeF₄**: Square planar (2 lone pairs) ### Final Answer The molecular shapes of SF₄, CF₄, and XeF₄ are seesaw, tetrahedral, and square planar, respectively.

To determine the molecular shapes of SF₄, CF₄, and XeF₄, we will follow these steps: ### Step 1: Determine the Steric Number for SF₄ 1. **Identify the central atom and its valence electrons**: Sulfur (S) has 6 valence electrons. 2. **Count the number of monovalent atoms attached**: There are 4 fluorine (F) atoms attached to sulfur. 3. **Calculate the steric number** using the formula: \[ \text{Steric Number} = \frac{(V + M)}{2} ...
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ICSE-CHEMICAL BONDING AND MOLECULAR STRUCTURE-OBJECTIVE ( MULTIPLE CHOICE ) TYPE QUESTIONS
  1. Which one of the following sets of ions represents the collection of i...

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  2. Lattice energy of an ionic compound depends on

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  3. The molecular shapes of SF4, CF4 and XeF4 are

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  4. Of the following sets which one does not contain isoelectronic species...

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  5. Which molecule/ ion out of the following does not contain unpaired ele...

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  6. Which one of the following sets of ions represents a collection of iso...

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  7. In which of the following molecule/ion all the bonds are not equal?

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  8. In which of the following ionisation processes, the bond order has inc...

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  9. Which of the following species exhibits the diamagnetic behaviour?

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  10. The calculated bond order of O(2)^(-) is

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  11. Which of the following is paramagnetic?

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  12. Which one of the following compounds has sp-hybridisation?

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  13. The calculated bond order in H(2)^(+) ion is

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  14. The bond order in the species O2, O(2)^(+) and O(2)^(-)follows the or...

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  15. Which of the following molecular orbitals has the lowest energy?

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  16. Among the following compounds the one that is polar and has the centra...

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  17. Oxygen molecule shows the property of :

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  18. Which has the bond order 1/2?

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  19. Which of the following is not a linear molecule?

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  20. Ammonia molecule is formed by the following hybrid orbitals:

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