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Among the following, the molecule expect...

Among the following, the molecule expected to be stabilized by anion formation is :
` C_2 ,O_2 , NO ,F_2`

A

`NO`

B

`O_(2)`

C

`C_2`

D

`F_2`

Text Solution

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The correct Answer is:
To determine which molecule among C₂, O₂, NO, and F₂ is expected to be stabilized by anion formation, we need to analyze the bond order of each molecule and how it changes upon the formation of an anion. ### Step-by-Step Solution: 1. **Understanding Bond Order**: The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of Bonding Electrons} - \text{Number of Anti-bonding Electrons})}{2} \] A higher bond order indicates greater stability of the molecule. 2. **Calculate Bond Order for C₂**: - C₂ has 12 electrons. - When it forms the anion (C₂⁻), it gains one additional electron, totaling 13 electrons. - In the molecular orbital configuration, C₂ has 9 bonding electrons and 4 anti-bonding electrons. - Thus, the bond order is: \[ \text{Bond Order}_{C_2} = \frac{(9 - 4)}{2} = \frac{5}{2} = 2.5 \] 3. **Calculate Bond Order for O₂**: - O₂ has 16 electrons. - When it forms the anion (O₂⁻), it gains one additional electron, totaling 17 electrons. - In the molecular orbital configuration, O₂ has 10 bonding electrons and 6 anti-bonding electrons. - Thus, the bond order is: \[ \text{Bond Order}_{O_2} = \frac{(10 - 6)}{2} = \frac{4}{2} = 2.0 \] 4. **Calculate Bond Order for NO**: - NO has 11 electrons. - When it forms the anion (NO⁻), it gains one additional electron, totaling 12 electrons. - In the molecular orbital configuration, NO has 7 bonding electrons and 5 anti-bonding electrons. - Thus, the bond order is: \[ \text{Bond Order}_{NO} = \frac{(7 - 5)}{2} = \frac{2}{2} = 1.0 \] 5. **Calculate Bond Order for F₂**: - F₂ has 18 electrons. - When it forms the anion (F₂⁻), it gains one additional electron, totaling 19 electrons. - In the molecular orbital configuration, F₂ has 10 bonding electrons and 9 anti-bonding electrons. - Thus, the bond order is: \[ \text{Bond Order}_{F_2} = \frac{(10 - 9)}{2} = \frac{1}{2} = 0.5 \] 6. **Comparison of Bond Orders**: - C₂: Bond Order = 2.5 - O₂: Bond Order = 2.0 - NO: Bond Order = 1.0 - F₂: Bond Order = 0.5 Among these, C₂ has the highest bond order, which indicates that it will be the most stabilized by anion formation. ### Conclusion: The molecule expected to be stabilized by anion formation is **C₂**.

To determine which molecule among C₂, O₂, NO, and F₂ is expected to be stabilized by anion formation, we need to analyze the bond order of each molecule and how it changes upon the formation of an anion. ### Step-by-Step Solution: 1. **Understanding Bond Order**: The bond order can be calculated using the formula: \[ \text{Bond Order} = \frac{(\text{Number of Bonding Electrons} - \text{Number of Anti-bonding Electrons})}{2} ...
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