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How can saline hydrides remove traces of...

How can saline hydrides remove traces of water from organic compounds?

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Saline hydrides (e.g., NaH, `CaH_(2)`, etc.) react with water at room temperature to form corresponding hydroxides with the liberation of `H_(2)` gas. Due to this property, they can be used to remove traces of water from organic compounds. The organic compound to be purified is distilled over a saline hydride when `H_(2)` escapes into the atmosphere and metal hydroxide is left in the residue left in the distillation flask. The organic compound free from moisture distils over.
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Assertion : Saline hydrides are non volatile, non conducting & crystalline solids. Reason : Saline hydrides are compounds of hydrogen with most of the p-block elements.

ICSE-HYDROGEN-NCERT TEXT-BOOK EXERCISE (With Hints and Solutions)
  1. What causes the temporary and permanent hardness of water ?

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  2. Discuss the principle and method of softening of hard water by synthet...

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  3. Write chemical reactions to show the amphoteric nature of water.

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  4. Write chemical reactions to justify that hydrogen peroxide can functio...

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  5. What is meant by demineralised water?

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  6. Is demineralised or distilled water useful for drinking purposes? If n...

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  7. Describe the usefulness of water in biosphere and biological systems.

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  8. What properties of water make it useful as a solvent? What types of co...

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  9. What properties of water make it useful as a solvent? What types of co...

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  10. Knowing the properties of H(2)O and D(2)O, do you think that D(2)O can...

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  11. What is the difference between the terms ‘hydrolysis’ and ‘hydration’ ...

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  12. How can saline hydrides remove traces of water from organic compounds?

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  13. What do you expect the nature of hydrides is, if formed by elements of...

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  14. Do you expect different products in solution when aluminium(III) chlor...

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  15. How does H(2)O(2) behave as a bleaching agent?

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  16. What do you understand by the terms: (i) hydrogen economy (ii) hydro...

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  17. What do you understand by the terms : hydrogenation

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  18. What do you understand by the terms : 'syngas'

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  19. What do you understand by the terms : water-gas shift reaction

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  20. What do you understand by the terms : fuel-cell ?

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