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Incorrect order of radius is:...

Incorrect order of radius is:

A

`Sr^(2+) lt Rb^(+) lt Br^(-) lt Se^(2-)`

B

`Nb^(5+) lt Zr^(4+) lt Y^(3+)`

C

`Co gt Co^(2+) gt Co^(3+) gt Co^(4+)`

D

`Ba^(2+) lt Cs^(+) lt Se^(2-) lt As^(3-)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the incorrect order of radius among the given options, we will analyze each option step by step. ### Step 1: Analyze Option A - **Given Species**: Strontium (Sr²⁺), Rubidium (Rb⁺), Bromine (Br⁻), Selenium (Se²⁻) - **Period**: Sr and Rb are in period 5, while Br and Se are in period 4. - **Isoelectronic Species**: When electrons are removed or added, we can form isoelectronic species. - **Effective Nuclear Charge (Z_eff)**: The atomic radius is inversely proportional to Z_eff. Thus, a higher positive charge leads to a smaller radius, while a higher negative charge leads to a larger radius. - **Order of Radius**: Se²⁻ > Br⁻ > Rb⁺ > Sr²⁺. This order is correct. ### Step 2: Analyze Option B - **Given Species**: Niobium (Nb⁵⁺), Zirconium (Zr⁴⁺), Ytterbium (Yb³⁺) - **Electrons**: All species have 36 electrons after ionization. - **Isoelectronic Species**: They are isoelectronic. - **Order of Radius**: Yb³⁺ > Zr⁴⁺ > Nb⁵⁺. This order is correct. ### Step 3: Analyze Option C - **Given Species**: Cobalt (Co), Cobalt (Co²⁺), Cobalt (Co³⁺), Cobalt (Co⁴⁺) - **Charge and Radius**: The atomic radius decreases with increasing positive charge. - **Order of Radius**: Co > Co²⁺ > Co³⁺ > Co⁴⁺. This order is correct. ### Step 4: Analyze Option D - **Given Species**: Barium (Ba²⁺), Cesium (Cs⁺), Selenium (Se²⁻), Arsenide (As³⁻) - **Period**: Ba and Cs are in period 6, while Se and As are in period 4. - **Not Isoelectronic**: Since they are not isoelectronic, we compare their atomic sizes based on their periods. - **Order of Radius**: Ba²⁺ and Cs⁺ will have larger radii compared to Se²⁻ and As³⁻. The expected order should be Cs⁺ > Ba²⁺ > Se²⁻ > As³⁻. This order is incorrect as it does not follow the expected trend. ### Conclusion The incorrect order of radius is found in **Option D**: Barium (Ba²⁺), Cesium (Cs⁺), Selenium (Se²⁻), and Arsenide (As³⁻). ### Final Answer **Option D** is the incorrect order of radius. ---

To determine the incorrect order of radius among the given options, we will analyze each option step by step. ### Step 1: Analyze Option A - **Given Species**: Strontium (Sr²⁺), Rubidium (Rb⁺), Bromine (Br⁻), Selenium (Se²⁻) - **Period**: Sr and Rb are in period 5, while Br and Se are in period 4. - **Isoelectronic Species**: When electrons are removed or added, we can form isoelectronic species. - **Effective Nuclear Charge (Z_eff)**: The atomic radius is inversely proportional to Z_eff. Thus, a higher positive charge leads to a smaller radius, while a higher negative charge leads to a larger radius. - **Order of Radius**: Se²⁻ > Br⁻ > Rb⁺ > Sr²⁺. This order is correct. ...
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