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The ionisation potential and electron af...

The ionisation potential and electron affinity of an element "X" are 275 and 86 kcal/mole. Then the electronegativity of "X" according to Mulliken scale is

A

2.8

B

0

C

4

D

2.6

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The correct Answer is:
To find the electronegativity of element "X" according to the Mulliken scale, we can follow these steps: ### Step 1: Understand the Formula The electronegativity (χ) according to the Mulliken scale is calculated using the formula: \[ \chi = \frac{I + A}{2} \] where: - \(I\) = Ionization Potential (IP) in kcal/mole - \(A\) = Electron Affinity (EA) in kcal/mole ### Step 2: Identify Given Values From the question, we have: - Ionization Potential (IP) = 275 kcal/mole - Electron Affinity (EA) = 86 kcal/mole ### Step 3: Substitute Values into the Formula Now, substitute the values of IP and EA into the formula: \[ \chi = \frac{275 + 86}{2} \] ### Step 4: Calculate the Sum Calculate the sum of the ionization potential and electron affinity: \[ 275 + 86 = 361 \] ### Step 5: Divide by 2 Now, divide the sum by 2 to find the electronegativity: \[ \chi = \frac{361}{2} = 180.5 \] ### Step 6: Final Calculation However, the Mulliken scale typically uses a different divisor, which is 129 (as mentioned in the video transcript). Therefore, we should actually calculate: \[ \chi = \frac{275 + 86}{129} \] Calculating this gives: \[ \chi = \frac{361}{129} \approx 2.8 \] ### Conclusion Thus, the electronegativity of element "X" according to the Mulliken scale is approximately **2.8**. ---

To find the electronegativity of element "X" according to the Mulliken scale, we can follow these steps: ### Step 1: Understand the Formula The electronegativity (χ) according to the Mulliken scale is calculated using the formula: \[ \chi = \frac{I + A}{2} \] where: ...
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