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The correct order of strength of H- bond...

The correct order of strength of `H-` bond in the following compound `:`

A

`H_(2)O gt H_(2)O_(2) gt HF gt H_(2)S`

B

`HF gt H_(2)O_(2) gt H_(2)O gt H_(2)S`

C

`HF gt H_(2)O gt H_(2)S gt H_(2)O_(2)`

D

`HF gt H_(2)O gt H_(2)O_(2) gt H_(2)S`

Text Solution

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The correct Answer is:
To determine the correct order of strength of hydrogen bonding in the given compounds, we will analyze the electronegativity of the atoms involved and the structure of each compound. ### Step-by-Step Solution: 1. **Understand Hydrogen Bonding**: - Hydrogen bonding occurs when hydrogen is bonded to a highly electronegative atom (like F, O, or N). The strength of hydrogen bonding is directly proportional to the electronegativity of the atom to which hydrogen is bonded. 2. **Identify the Compounds**: - The compounds we are comparing are HF (Hydrogen Fluoride), H2O (Water), H2O2 (Hydrogen Peroxide), and H2S (Hydrogen Sulfide). 3. **Evaluate Electronegativity**: - The electronegativities of the relevant atoms are as follows: - Fluorine (F): Highest electronegativity - Oxygen (O): Moderate electronegativity - Sulfur (S): Lowest electronegativity - Therefore, the order of electronegativity is: F > O > S. 4. **Analyze Each Compound**: - **HF**: The hydrogen bond is very strong because fluorine has the highest electronegativity. - **H2O**: Water has strong hydrogen bonds due to the presence of oxygen, which is also highly electronegative. - **H2O2**: Hydrogen peroxide has weaker hydrogen bonds compared to water because it has a lower effective electronegativity due to the presence of an additional oxygen atom which reduces the overall electronegativity effect. - **H2S**: Hydrogen sulfide has the weakest hydrogen bonds because sulfur is the least electronegative of the atoms involved. 5. **Rank the Compounds**: - Based on the above analysis, we can rank the compounds in order of hydrogen bonding strength: - 1st: HF (strongest) - 2nd: H2O - 3rd: H2O2 - 4th: H2S (weakest) 6. **Final Order**: - The correct order of strength of hydrogen bonding in the compounds is: - HF > H2O > H2O2 > H2S

To determine the correct order of strength of hydrogen bonding in the given compounds, we will analyze the electronegativity of the atoms involved and the structure of each compound. ### Step-by-Step Solution: 1. **Understand Hydrogen Bonding**: - Hydrogen bonding occurs when hydrogen is bonded to a highly electronegative atom (like F, O, or N). The strength of hydrogen bonding is directly proportional to the electronegativity of the atom to which hydrogen is bonded. 2. **Identify the Compounds**: ...
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VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
  1. The correct order of strength of H- bond in the following compound :

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  2. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

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  3. Consider the following five group (According to modern periodic table)...

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  4. Consider the following species and find out total number of species wh...

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  5. Consider the following table regarding interhalogen compounds, XY(n) (...

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  6. What is covalency of chlorine atom in second excited state ?

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  7. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  8. Calculate the value of X-Y, for XeOF(4). (X=Number of sigma bond pair ...

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  9. The molecule ABn is planar with six pairs of electrons around A in the...

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  10. Calculate value of (X+Y+Z)/(10), here X is O-N-O bond angle in NO(3)^(...

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  11. Calculate x+y+z for H(3)PO(3) acid, where x is no. of lone pairs, y is...

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  12. How many right angle, bond angles are present in TeF(5)^(-) molecular ...

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  13. How may possible angle FSeF bond angles are present in SeF(4) molecule...

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  14. In IF(6)^(-) and TeF(5)^(-), sum of axial d-orbitals which are used in...

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  15. Among the following, total no. of planar species is : (i) SF(4) " "...

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  16. Calculate the value of " x+y-z" here x,y and z are total number of non...

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  17. Consider the following table Then calculate value of "p+q+r-s-t".

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  18. In phosphorus acid, if X is number of non bonding electron pairs. Y is...

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  19. Calculate the number of p(pi)-d(pi) bond(s) present in SO(4)^(2-) :

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  20. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  21. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

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