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Choose the correct code of characteristi...

Choose the correct code of characteristics for the given order of hybrid orbitals of same atom,
`sp lt sp^(2) lt sp^(3)`
(i) Electrongativity (ii) Bond angle between same hybrid orbitals
(iii) Size (iv) Energy level

A

ii, iii and iv

B

iii, iv

C

ii and iv

D

I, ii, iii and iv

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the characteristics of the hybrid orbitals in the order \( sp < sp^2 < sp^3 \), we will analyze each characteristic one by one. ### Step-by-Step Solution: 1. **Electronegativity**: - Electronegativity is influenced by the s-character of the hybrid orbitals. The more s-character an orbital has, the higher its electronegativity. - The order of s-character is: - \( sp \) (50% s-character) > \( sp^2 \) (33% s-character) > \( sp^3 \) (25% s-character). - Therefore, the correct order for electronegativity is: \[ \text{Electronegativity: } sp > sp^2 > sp^3 \] - Since the question gives \( sp < sp^2 < sp^3 \), this option is incorrect. 2. **Bond Angle Between Same Hybrid Orbitals**: - The bond angles for the hybrid orbitals are: - \( sp \): 180° - \( sp^2 \): 120° - \( sp^3 \): 109.5° - The order of bond angles is: \[ \text{Bond Angle: } sp > sp^2 > sp^3 \] - Again, the question provides \( sp < sp^2 < sp^3 \), making this option incorrect. 3. **Size**: - The size of the hybrid orbitals is inversely related to the s-character. More s-character leads to a more compact and smaller size. - Thus, the order of size is: \[ \text{Size: } sp < sp^2 < sp^3 \] - This matches the order given in the question, so this option is correct. 4. **Energy Level**: - The energy level of hybrid orbitals increases with the increase in p-character. Since s orbitals are lower in energy than p orbitals: - The order of energy levels is: \[ \text{Energy Level: } sp < sp^2 < sp^3 \] - This also matches the order given in the question, making this option correct. ### Conclusion: From the analysis: - The correct characteristics for the order \( sp < sp^2 < sp^3 \) are: - Size: Correct - Energy Level: Correct - Electronegativity: Incorrect - Bond Angle: Incorrect Thus, the correct codes for the characteristics are **(iii) Size and (iv) Energy Level**.
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