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A molecule XY(2) contains two sigma bond...

A molecule `XY_(2)` contains two `sigma` bonds two `pi` bond and one lone pair of electrons in the valence shell of `X`. The arrangement of lone pair as well as bond pairs is

A

square pyramidal

B

linear

C

Trigonal planar

D

unpredictable

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The correct Answer is:
To determine the arrangement of lone pairs and bond pairs in the molecule \( XY_2 \) with the given characteristics, we can follow these steps: ### Step 1: Analyze the given information The molecule \( XY_2 \) has: - 2 sigma bonds - 2 pi bonds - 1 lone pair of electrons on the central atom \( X \) ### Step 2: Determine the hybridization of the central atom \( X \) Given that there are 2 sigma bonds and 2 pi bonds, we can deduce the hybridization: - Each sigma bond corresponds to one hybrid orbital. - Each pi bond corresponds to unhybridized p orbitals. Since there are 2 sigma bonds and 2 pi bonds, the central atom \( X \) must be involved in sp hybridization: - In sp hybridization, there are 2 hybrid orbitals (for the 2 sigma bonds) and 2 unhybridized p orbitals (for the 2 pi bonds). ### Step 3: Consider the lone pair With 1 lone pair of electrons on \( X \), we need to account for this in the geometry: - The presence of a lone pair will affect the molecular geometry. ### Step 4: Determine the molecular geometry In sp hybridization with 2 sigma bonds and 1 lone pair, the arrangement of the electron pairs (both bonding and lone pairs) will adopt a linear geometry. This is because: - The 2 sigma bonds will be 180 degrees apart, and the lone pair will occupy one of the positions in a way that minimizes repulsion. ### Step 5: Final arrangement Thus, the arrangement of the lone pair and bond pairs in \( XY_2 \) is linear. ### Conclusion The arrangement of lone pairs and bond pairs in the molecule \( XY_2 \) is linear. ---
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