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Assertion : Xe-atom in XeF(2) assumes sp...

Assertion : Xe-atom in `XeF_(2)` assumes sp-hybrid state.
Reason : `XeF_(2)` molecule does not follow octet rule.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

IF both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

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AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason about the hybridization of the xenon atom in \(XeF_2\) and its adherence to the octet rule, we can break it down step by step. ### Step-by-Step Solution: 1. **Identify the Assertion and Reason**: - Assertion: The xenon atom in \(XeF_2\) assumes an sp-hybrid state. - Reason: The \(XeF_2\) molecule does not follow the octet rule. 2. **Determine the Valence Electrons of Xenon**: - Xenon (Xe) is a noble gas and has 8 valence electrons. 3. **Analyze the Bonding in \(XeF_2\)**: - In \(XeF_2\), xenon forms two bonds with fluorine atoms. Each fluorine atom contributes one electron to form a covalent bond with xenon. - Thus, 2 electrons are used for bonding, leaving \(8 - 2 = 6\) electrons. 4. **Count Lone Pairs**: - The remaining 6 electrons will be present as lone pairs on the xenon atom. - Therefore, xenon has 3 lone pairs (since each lone pair consists of 2 electrons). 5. **Determine the Hybridization**: - The total number of electron pairs around the xenon atom is the sum of bond pairs and lone pairs: - Bond pairs = 2 (from \(Xe-F\) bonds) - Lone pairs = 3 - Total = 2 + 3 = 5 - The hybridization corresponding to 5 electron pairs is \(sp^3d\). 6. **Evaluate the Assertion**: - Since the assertion states that xenon assumes an sp-hybrid state, and we found it to be \(sp^3d\), the assertion is **false**. 7. **Evaluate the Reason**: - The reason states that \(XeF_2\) does not follow the octet rule. - In \(XeF_2\), xenon has 10 electrons in its valence shell (2 from each fluorine and 6 as lone pairs), which indeed makes it a hypervalent compound. Thus, the reason is **true**. 8. **Conclusion**: - The assertion is false, and the reason is true. Therefore, the correct option is that the assertion is false, but the reason is true. ### Final Answer: - Assertion: False - Reason: True
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