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Assertion : Geometry of IC l(3) is tetra...

Assertion : Geometry of `IC l_(3)` is tetrahedral.
Reason : Its shape is T-shape, due to the presence of two lone pairs.

A

assertion is true but the reason is false

B

assertion is false but reason is true

C

both assertion and reason are true and the reason is the correct explanation of assertion

D

both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
### Step-by-Step Solution: 1. **Identify the Compound**: The compound in question is ICl3 (Iodine trichloride). 2. **Determine the Valence Electrons**: - Iodine (I) has 7 valence electrons. - Each Chlorine (Cl) has 7 valence electrons, and there are 3 Cl atoms contributing a total of 21 electrons. - Total valence electrons = 7 (from I) + 21 (from 3 Cl) = 28 valence electrons. 3. **Draw the Lewis Structure**: - Iodine is the central atom and forms single bonds with three chlorine atoms. - Each bond uses 2 electrons, so 3 bonds use 6 electrons. - Remaining electrons = 28 - 6 = 22 electrons. - These remaining electrons will be placed as lone pairs on the central iodine atom. 4. **Count Lone Pairs**: - After forming 3 bonds, there are 4 electrons left, which means there are 2 lone pairs on the iodine atom. 5. **Determine the Steric Number**: - The steric number (Z) is the sum of bond pairs and lone pairs. - In ICl3, there are 3 bond pairs and 2 lone pairs, so Z = 3 + 2 = 5. 6. **Identify Hybridization**: - With a steric number of 5, the hybridization is sp³d. 7. **Determine the Geometry**: - The geometry for a steric number of 5 is trigonal bipyramidal. 8. **Determine the Molecular Shape**: - In the trigonal bipyramidal geometry, the two lone pairs will occupy the equatorial positions to minimize repulsion, resulting in a T-shaped molecular geometry for ICl3. 9. **Evaluate the Assertion and Reason**: - **Assertion**: "Geometry of ICl3 is tetrahedral" - This is **false**. - **Reason**: "Its shape is T-shape, due to the presence of two lone pairs" - This is **true**. 10. **Conclusion**: - The assertion is false, but the reason is true. Therefore, the correct option is that the assertion is false and the reason is true.
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