Home
Class 12
CHEMISTRY
Calculate the value of " x+y-z" here x,y...

Calculate the value of " x+y-z" here x,y and z are total number of non-bonded electron pair (s),pie `(pi)` bond(s) and sigma `(sigma)` bonds in hydrogen phosphite ion respectively.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the values of \(x\), \(y\), and \(z\) for the hydrogen phosphite ion, \(H_2PO_3^-\). ### Step 1: Identify the structure of hydrogen phosphite ion The molecular formula for hydrogen phosphite is \(H_2PO_3^-\). The structure can be visualized as follows: - The phosphorus (P) atom is bonded to three oxygen (O) atoms. - One of the oxygen atoms is bonded to a hydrogen (H) atom, and one oxygen carries a negative charge. ### Step 2: Count the non-bonded electron pairs (x) In the structure: - Each oxygen atom typically has 6 valence electrons. - The oxygen that is bonded to hydrogen (OH) has 2 lone pairs. - The negatively charged oxygen (O^-) has 3 lone pairs. - The other oxygen (double bonded to phosphorus) has 2 lone pairs. Counting the lone pairs: - Oxygen with H: 2 lone pairs - Oxygen with negative charge: 3 lone pairs - Double bonded oxygen: 2 lone pairs Total non-bonded electron pairs: \[ x = 2 + 3 + 2 = 7 \] ### Step 3: Count the number of pi bonds (y) In the structure, there is one double bond between phosphorus and one of the oxygen atoms. A double bond consists of one sigma bond and one pi bond. Thus, the number of pi bonds: \[ y = 1 \] ### Step 4: Count the number of sigma bonds (z) Now, we will count the sigma bonds in the structure: - The P-O double bond contributes 1 sigma bond. - The P-O single bond contributes 1 sigma bond. - The P-H bond contributes 1 sigma bond. - The O-H bond contributes 1 sigma bond. - The O with a negative charge also contributes 1 sigma bond. Counting all the sigma bonds: \[ z = 5 \] ### Step 5: Calculate \(x + y - z\) Now we can substitute the values we found into the expression \(x + y - z\): \[ x + y - z = 7 + 1 - 5 \] \[ x + y - z = 3 \] ### Final Answer The value of \(x + y - z\) is \(3\). ---

To solve the problem, we need to determine the values of \(x\), \(y\), and \(z\) for the hydrogen phosphite ion, \(H_2PO_3^-\). ### Step 1: Identify the structure of hydrogen phosphite ion The molecular formula for hydrogen phosphite is \(H_2PO_3^-\). The structure can be visualized as follows: - The phosphorus (P) atom is bonded to three oxygen (O) atoms. - One of the oxygen atoms is bonded to a hydrogen (H) atom, and one oxygen carries a negative charge. ### Step 2: Count the non-bonded electron pairs (x) ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|23 Videos
  • CHEMICAL BONDING (ADVANCED)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|64 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise LEVEL 2|144 Videos

Similar Questions

Explore conceptually related problems

Number of sigma and pi bonds in anthracene will be equal to respectively

Calculate value of "x+y" ffor "hypophoshporic acid", where x is total number of lone pair(s) and y is total number pi -bond(s) in givenn oxo-acids.

The number of sigma and pi bonds in peroxydisulphuric acid are, respectively.

Calculate value of |x-y|, here x and y are the total number of bonds in benzene and benzyne respectively which are formed by overlapping of hybridized orbitals.

The number of sigma - and pi -bond in hexan-2,4-diol, respectively,is:

Calculate the value of X-Y, for XeOF_(4) . (X=Number of sigma bond pair and Y=Number of lone pair on central atom )

The number of sigma (sigma) and pi (pi) bonds present in acetylene are _____ respectively.

The number of sigma - and pi -bond in 5-oxohexanoic acid, respectively, is :

Calculate value of "x+y" if x is the total number of sigma bonds and y is total number of pi bonds in ligand EDTA and phenanthrolene. (EDTA Ethylene diamine tetraacetate, Phen=1,10-N,N-phenanthrolene)

Calculate value of "x+y" if x is the total number of sigma bonds and y is total number of pi bonds in ligand EDTA and phenanthrolene. (EDTA Ethylene diamine tetraacetate, Phen=1,10-N,N-phenanthrolene)

VK JAISWAL ENGLISH-CHEMICAL BONDING (BASIC)-SUBJECTIVE PROBLEMS
  1. In IF(6)^(-) and TeF(5)^(-), sum of axial d-orbitals which are used in...

    Text Solution

    |

  2. Among the following, total no. of planar species is : (i) SF(4) " "...

    Text Solution

    |

  3. Calculate the value of " x+y-z" here x,y and z are total number of non...

    Text Solution

    |

  4. Consider the following table Then calculate value of "p+q+r-s-t".

    Text Solution

    |

  5. In phosphorus acid, if X is number of non bonding electron pairs. Y is...

    Text Solution

    |

  6. Calculate the number of p(pi)-d(pi) bond(s) present in SO(4)^(2-) :

    Text Solution

    |

  7. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

    Text Solution

    |

  8. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

    Text Solution

    |

  9. Calculate value of |x-y|, here x and y are the total number of bonds i...

    Text Solution

    |

  10. Consider the following compounds: (i)IF(5) (ii)ClI(4)^(-) (iii)XeO...

    Text Solution

    |

  11. Total number of species which used all three p-orbitals in hybridisati...

    Text Solution

    |

  12. Consider the following species NO(3)^(-), SO(4)^(2-), ClO(3)^(-),SO(3)...

    Text Solution

    |

  13. Consider the following orbitals 3s, 2p(x), 4d(xy),4d(z^(2)), 3d(x^(2)-...

    Text Solution

    |

  14. For the following molecules : PCl(5), BrF(3), IC l(2)^(-), XeF(5)^(-...

    Text Solution

    |

  15. Find out number of transformation among following which involves the c...

    Text Solution

    |

  16. Consider following compounds A to E : (A) XeF(n) " " (B) XeF((n+1)...

    Text Solution

    |

  17. Consider the following five group (According to modern periodic table)...

    Text Solution

    |

  18. Consider the following species and find out total number of species wh...

    Text Solution

    |

  19. Consider the following table regarding interhalogen compounds, XY(n) (...

    Text Solution

    |

  20. What is covalency of chlorine atom in second excited state ?

    Text Solution

    |