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Consider the following orbitals (i)3p(x)...

Consider the following orbitals (i)`3p_(x)` (ii)`4d_(z^(2))` (iii)`3d_(x^(2)-y^(2))` (iv)`3d_(yz)`
Then, calculate value of "`x+y-z`" here x is total number of gerade orbital and y is total number of ungerade orbitals and z is total number of axial orbitals in given above orbitals.

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To solve the problem, we will analyze each of the given orbitals and categorize them into gerade and ungerade orbitals, as well as identify the axial orbitals. ### Step-by-Step Solution: 1. **Identify the Orbitals**: - The orbitals given are: - (i) `3p_x` - (ii) `4d_{z^2}` - (iii) `3d_{x^2-y^2}` - (iv) `3d_{yz}` 2. **Define Terms**: - **Gerade Orbitals**: These are symmetric with respect to inversion through the origin. - **Ungerade Orbitals**: These are not symmetric with respect to inversion. - **Axial Orbitals**: These are orbitals that lie along the principal axes (x, y, z). 3. **Analyze Each Orbital**: - **(i) `3p_x`**: - This orbital is not symmetric with respect to inversion (positive phase on one side and negative on the other). - **Classification**: Ungerade - **Axial**: Yes (along the x-axis) - **(ii) `4d_{z^2}`**: - This orbital is symmetric with respect to inversion (both lobes are positive). - **Classification**: Gerade - **Axial**: Yes (along the z-axis) - **(iii) `3d_{x^2-y^2}`**: - This orbital is symmetric with respect to inversion (positive lobes in the x and y directions). - **Classification**: Gerade - **Axial**: Yes (along the x and y axes) - **(iv) `3d_{yz}`**: - This orbital is not symmetric with respect to inversion (positive and negative lobes). - **Classification**: Ungerade - **Axial**: No (lobes are in the yz plane, not along an axis) 4. **Count the Orbitals**: - **Total Gerade Orbitals (x)**: - `4d_{z^2}` and `3d_{x^2-y^2}` → 2 - **Total Ungerade Orbitals (y)**: - `3p_x` and `3d_{yz}` → 2 - **Total Axial Orbitals (z)**: - `3p_x`, `4d_{z^2}`, and `3d_{x^2-y^2}` → 3 5. **Calculate x + y - z**: - Substitute the values: - x = 2 (gerade) - y = 2 (ungerade) - z = 3 (axial) - Calculation: \[ x + y - z = 2 + 2 - 3 = 1 \] ### Final Answer: The value of \( x + y - z \) is **1**.

To solve the problem, we will analyze each of the given orbitals and categorize them into gerade and ungerade orbitals, as well as identify the axial orbitals. ### Step-by-Step Solution: 1. **Identify the Orbitals**: - The orbitals given are: - (i) `3p_x` - (ii) `4d_{z^2}` ...
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  2. Sum of sigma and pi bonds in NH(4)^(+) cation is ..

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  3. Consider the following orbitals (i)3p(x) (ii)4d(z^(2)) (iii)3d(x^(2)...

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  6. Total number of species which used all three p-orbitals in hybridisati...

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  9. For the following molecules : PCl(5), BrF(3), IC l(2)^(-), XeF(5)^(-...

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  17. Calculate the value of X-Y, for XeOF(4). (X=Number of sigma bond pair ...

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