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Assertion: C(3)O(2) has linear structure...

Assertion: `C_(3)O_(2)` has linear structure.
Reason: Each carbon atom in `C_(3)O_(2)` in `sp` -hydridized.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true and the reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion and reason statements regarding \( C_3O_2 \), we will break down the problem step by step. ### Step 1: Understand the Assertion The assertion states that \( C_3O_2 \) has a linear structure. To verify this, we need to examine the molecular structure of \( C_3O_2 \), which is known as carbon suboxide. ### Step 2: Draw the Structure of \( C_3O_2 \) The structure of \( C_3O_2 \) can be represented as follows: - The molecule consists of three carbon atoms and two oxygen atoms. - The arrangement is: \( O=C=C=C=O \). - This indicates that the carbon atoms are connected by double bonds, and the terminal carbon atoms are each double-bonded to an oxygen atom. ### Step 3: Determine the Hybridization of Carbon Atoms Next, we analyze the hybridization of the carbon atoms in \( C_3O_2 \): - Each carbon atom is involved in two sigma bonds (one with the adjacent carbon and one with the oxygen). - The presence of double bonds means that there are also pi bonds, but these do not contribute to hybridization. - Therefore, each carbon atom has a steric number of 2 (2 sigma bonds), which indicates that they are \( sp \)-hybridized. ### Step 4: Confirm the Structure Since each carbon atom is \( sp \)-hybridized and there are no lone pairs on the carbon atoms, the molecular geometry is linear. This confirms the assertion that \( C_3O_2 \) has a linear structure. ### Step 5: Analyze the Reason The reason states that each carbon atom in \( C_3O_2 \) is \( sp \)-hybridized. We have established that this is indeed true, as each carbon atom has a steric number of 2. ### Step 6: Conclusion Both the assertion and the reason are true: - Assertion: \( C_3O_2 \) has a linear structure (True). - Reason: Each carbon atom in \( C_3O_2 \) is \( sp \)-hybridized (True). Furthermore, the reason correctly explains the assertion because \( sp \)-hybridization leads to a linear geometry. ### Final Answer Both the assertion and reason are true, and the reason correctly explains the assertion. ---
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