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EAN of a metal carbonyl M(CO)(x) is 36. ...

EAN of a metal carbonyl `M(CO)_(x)` is 36. If atomic number of metal M is 26, what is the value of x?

A

5

B

4

C

6

D

none of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the value of \( x \) in the metal carbonyl \( M(CO)_{x} \) given that the Effective Atomic Number (EAN) is 36 and the atomic number of the metal \( M \) is 26. ### Step-by-Step Solution: 1. **Understand the Formula for EAN**: The Effective Atomic Number (EAN) can be calculated using the formula: \[ \text{EAN} = Z - n + 2 \times C \] where: - \( Z \) = Atomic number of the metal - \( n \) = Oxidation state of the metal - \( C \) = Coordination number (number of ligands) 2. **Identify Given Values**: From the problem: - EAN = 36 - Atomic number \( Z \) = 26 (for metal \( M \)) - For carbonyl ligands (CO), the oxidation state \( n \) of the metal is 0. 3. **Substituting Known Values into the EAN Formula**: Substitute the known values into the EAN formula: \[ 36 = 26 - 0 + 2 \times C \] This simplifies to: \[ 36 = 26 + 2C \] 4. **Rearranging the Equation**: Rearranging the equation to solve for \( C \): \[ 36 - 26 = 2C \] \[ 10 = 2C \] 5. **Solving for Coordination Number \( C \)**: Divide both sides by 2: \[ C = \frac{10}{2} = 5 \] 6. **Conclusion**: Therefore, the value of \( x \) (the number of carbonyl ligands) is 5. ### Final Answer: The value of \( x \) is 5.
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