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Complexes formed in the following method...

Complexes formed in the following methods are:
(I) Mond's process for purification of nickel
(II) Removal of ureacted AgBr from photographic plate
(III) Removal of lead poisoning from the body

A

`{:(I,II,III),(Ni(CO)_(4),[Ag(CN)_(2)]^(-),[Pb(EDTA)]^(2-)):}`

B

`{:(I,II,III),(Ni(CO)_(4),[Ag(S_(2)O_(3))_(2)]^(3-),[Pb(EDTA)]^(2-)):}`

C

`{:(I,II,III),(Ni(CO)_(6),Ag(S_(2)O_(3))_(2)]^(3-),([Pb(EDTA)]^(4-)):}`

D

`{:(I,II,III),(Ni(CO)_(6),[Ag(S_(2)O_(3))]^(-),[Pb(EDTA)]^(2-)):}`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the complexes formed in the specified methods, we will analyze each method step by step. ### Step 1: Mond's Process for Purification of Nickel - **Process Description**: In Mond's process, impure nickel is reacted with carbon monoxide (CO) at a temperature of 330 to 350 Kelvin. - **Complex Formation**: The reaction forms a volatile complex known as nickel tetracarbonyl. - **Chemical Equation**: \[ \text{Ni (s) + 4 CO (g) } \rightarrow \text{ Ni(CO)_4 (g)} \] - **Final Complex**: The complex formed is **Ni(CO)₄**. ### Step 2: Removal of Unreacted AgBr from Photographic Plate - **Process Description**: After developing a photographic plate, unreacted silver bromide (AgBr) needs to be removed. This is typically done using a hypo solution (sodium thiosulfate). - **Complex Formation**: The hypo solution reacts with AgBr to form a soluble complex. - **Chemical Equation**: \[ \text{AgBr (s) + 2 Na_2S_2O_3 (aq)} \rightarrow \text{Na_3[Ag(S_2O_3)_2] (aq) + NaBr (aq)} \] - **Final Complex**: The complex formed is **Na₃[Ag(S₂O₃)₂]**. ### Step 3: Removal of Lead Poisoning from the Body - **Process Description**: Lead poisoning can be treated by chelation therapy, where a chelating agent is used to bind lead ions and facilitate their excretion from the body. - **Complex Formation**: Ethylenediaminetetraacetic acid (EDTA) is commonly used for this purpose. - **Chemical Equation**: \[ \text{Pb}^{2+} (aq) + \text{EDTA}^{4-} (aq) \rightarrow \text{[Pb(EDTA)]}^{2-} (aq) \] - **Final Complex**: The complex formed is **[Pb(EDTA)]²⁻**. ### Summary of Complexes Formed 1. **Mond's Process**: Ni(CO)₄ 2. **Removal of AgBr**: Na₃[Ag(S₂O₃)₂] 3. **Lead Poisoning Treatment**: [Pb(EDTA)]²⁻ ### Final Answer The complexes formed in the methods are: - (I) Ni(CO)₄ - (II) Na₃[Ag(S₂O₃)₂] - (III) [Pb(EDTA)]²⁻

To solve the question regarding the complexes formed in the specified methods, we will analyze each method step by step. ### Step 1: Mond's Process for Purification of Nickel - **Process Description**: In Mond's process, impure nickel is reacted with carbon monoxide (CO) at a temperature of 330 to 350 Kelvin. - **Complex Formation**: The reaction forms a volatile complex known as nickel tetracarbonyl. - **Chemical Equation**: \[ \text{Ni (s) + 4 CO (g) } \rightarrow \text{ Ni(CO)_4 (g)} ...
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
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  2. Which of the following ligand does not as pi-acid ligand?

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  3. If EAN of central metal cation M^(2+) in an non-chelating complex is 3...

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  4. [Mn(CO)(4)NO] is diamagnetic because:

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  5. Choose the correct option regarding the following complex compound whi...

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  6. If CO ligands are substituted by NO in respective neutral carbonyl com...

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  7. Which of the following species can act as reducing agent ?

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  8. If Delta(0) lt P, the correct electronic configuration for d^(4) syste...

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  9. Which of the following statement is not correct?

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  10. Give the correct of initials T or F for following statements. Use T if...

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  11. match List-I with list-II and select the correct answer using the code...

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  12. The value of 'spin only' magnetic moment for one of the following conf...

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  13. The correct order of magnetic moments (spin values in B.M.) among is:

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  14. Which of the following statements is incorrect?

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  15. Set of d-orbitals which is used by central metal during formation of M...

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  16. FeSO(4) is a very good absorber for NO, the new compound formed by thi...

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  17. A [M(H(2)O)(6)]^(2+) complex typically absorbs at around 600 n. it is ...

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  18. Given that the energy of the photons of different colours decreases in...

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  19. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1) . The CFSE fo...

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  20. MnO(4)^(-) is of intense pink colour, though Mn is in(+7) oxidation st...

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  21. In which of the following complex ion the value of magnetic moment (sp...

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