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The IUPAC name for [PtCl(NH(2)CH(3))(NH(...

The IUPAC name for `[PtCl(NH_(2)CH_(3))(NH_(3))_(2)]Cl` is:

A

diamminechloro(methylamine)platinum(II)chloride

B

(dimethylamine)chlorodiamminoplatinum(II)chloride

C

bis(ammine)chloro(methylamine)platinate(II)chloride

D

diaminechloro(methylamine)platinum(II)chloride

Text Solution

AI Generated Solution

The correct Answer is:
To determine the IUPAC name for the coordination compound \([PtCl(NH_2CH_3)(NH_3)_2]Cl\), we will follow a systematic approach. Here’s a step-by-step breakdown: ### Step 1: Identify the Central Metal Atom The central metal atom in the coordination compound is platinum (Pt). ### Step 2: Identify the Ligands The ligands attached to the platinum are: - Chloride ion (Cl⁻) - Methylamine (NH₂CH₃) - Two ammonia (NH₃) molecules ### Step 3: Name the Ligands - The chloride ligand is named "chloro." - Methylamine is named "methylamine." - Ammonia is named "ammine." ### Step 4: Determine the Number of Each Ligand - There is one chloride ligand (chloro). - There are two ammonia ligands (ammine). - There is one methylamine ligand (methylamine). ### Step 5: Write the Ligands in Alphabetical Order When naming the ligands, we arrange them in alphabetical order regardless of their prefixes: 1. Amine (ammine) 2. Chloro 3. Methylamine ### Step 6: Determine the Oxidation State of the Metal Let the oxidation state of platinum be \(x\). The charges from the ligands are: - Chloride (Cl) contributes -1 - Methylamine (NH₂CH₃) is neutral (0) - Ammonia (NH₃) is neutral (0) The overall charge of the coordination complex is +1 (due to the external chloride ion). Therefore, we can set up the equation: \[ x + (-1) + 0 + 0 = +1 \] Solving for \(x\): \[ x - 1 = 1 \] \[ x = 2 \] Thus, the oxidation state of platinum is +2. ### Step 7: Combine the Names Now, we can combine the names of the ligands with the name of the metal and its oxidation state: - Ligands: "diammine" (for two NH₃), "chloro," "methylamine" - Metal: "platinum" - Oxidation state: (II) ### Step 8: Write the Full Name Putting it all together, we get: **IUPAC Name: diamminechloro(methylamine)platinum(II) chloride** ### Final Answer The IUPAC name for \([PtCl(NH_2CH_3)(NH_3)_2]Cl\) is: **diamminechloro(methylamine)platinum(II) chloride** ---
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
  1. The IUPAC name for [PtCl(NH(2)CH(3))(NH(3))(2)]Cl is:

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  2. Which of the following ligand does not as pi-acid ligand?

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  3. If EAN of central metal cation M^(2+) in an non-chelating complex is 3...

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  4. [Mn(CO)(4)NO] is diamagnetic because:

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  5. Choose the correct option regarding the following complex compound whi...

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  6. If CO ligands are substituted by NO in respective neutral carbonyl com...

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  7. Which of the following species can act as reducing agent ?

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  8. If Delta(0) lt P, the correct electronic configuration for d^(4) syste...

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  9. Which of the following statement is not correct?

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  10. Give the correct of initials T or F for following statements. Use T if...

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  11. match List-I with list-II and select the correct answer using the code...

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  12. The value of 'spin only' magnetic moment for one of the following conf...

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  13. The correct order of magnetic moments (spin values in B.M.) among is:

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  14. Which of the following statements is incorrect?

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  15. Set of d-orbitals which is used by central metal during formation of M...

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  16. FeSO(4) is a very good absorber for NO, the new compound formed by thi...

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  17. A [M(H(2)O)(6)]^(2+) complex typically absorbs at around 600 n. it is ...

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  18. Given that the energy of the photons of different colours decreases in...

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  19. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1) . The CFSE fo...

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  20. MnO(4)^(-) is of intense pink colour, though Mn is in(+7) oxidation st...

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  21. In which of the following complex ion the value of magnetic moment (sp...

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