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[Mn(CO)(4)NO] is diamagnetic because:...

`[Mn(CO)_(4)NO]` is diamagnetic because:

A

Mn metal is diamagnetiic in free state

B

Mn is in +1 oxidation state in this complex

C

No is present as positive ligand

D

All of these

Text Solution

Verified by Experts

The correct Answer is:
D

`[overset(+1)(Mn)(CO)_(4)(NO^(-))]`: Paramagnetic due to presence of unpaired `e^(-)` s in `NO^(-)`
`[overset(-1)(Mn)(CO)_(4)(NO^(+))]:`No unpaired `e^(-)` either on ligands or on `overset(-1)(Mn)` hence it is diamagnetic.
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
  1. Which of the following ligand does not as pi-acid ligand?

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  2. If EAN of central metal cation M^(2+) in an non-chelating complex is 3...

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  3. [Mn(CO)(4)NO] is diamagnetic because:

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  4. Choose the correct option regarding the following complex compound whi...

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  5. If CO ligands are substituted by NO in respective neutral carbonyl com...

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  6. Which of the following species can act as reducing agent ?

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  7. If Delta(0) lt P, the correct electronic configuration for d^(4) syste...

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  8. Which of the following statement is not correct?

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  9. Give the correct of initials T or F for following statements. Use T if...

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  10. match List-I with list-II and select the correct answer using the code...

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  11. The value of 'spin only' magnetic moment for one of the following conf...

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  12. The correct order of magnetic moments (spin values in B.M.) among is:

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  13. Which of the following statements is incorrect?

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  14. Set of d-orbitals which is used by central metal during formation of M...

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  15. FeSO(4) is a very good absorber for NO, the new compound formed by thi...

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  16. A [M(H(2)O)(6)]^(2+) complex typically absorbs at around 600 n. it is ...

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  17. Given that the energy of the photons of different colours decreases in...

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  18. The CFSE for octahedral [CoCl(6)]^(4-) is 18,000 cm^(-1) . The CFSE fo...

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  19. MnO(4)^(-) is of intense pink colour, though Mn is in(+7) oxidation st...

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  20. In which of the following complex ion the value of magnetic moment (sp...

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