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The value of 'spin only' magnetic moment...

The value of 'spin only' magnetic moment for one of the following configuration is `2.84B.M.` The correct one is:

A

`d^(4)` (in strong field ligand)

B

`d^(2)` (in weak field ligand)

C

`d^(3)` (In weak as well as in strong field ligand)

D

`d^(5)` (in strong field ligand)

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The correct Answer is:
To solve the question regarding the value of 'spin only' magnetic moment being `2.84 B.M.`, we need to analyze the given configurations and determine which one corresponds to this magnetic moment value. The magnetic moment can be calculated using the formula: \[ \mu = \sqrt{n(n + 2)} \] where \( n \) is the number of unpaired electrons. ### Step-by-Step Solution: 1. **Understanding the Magnetic Moment Formula**: - The formula for calculating the spin-only magnetic moment is given as \(\mu = \sqrt{n(n + 2)}\). - We need to find the value of \( n \) (the number of unpaired electrons) that will give us a magnetic moment of `2.84 B.M.`. 2. **Calculate the Number of Unpaired Electrons**: - We set up the equation: \[ \sqrt{n(n + 2)} = 2.84 \] - Squaring both sides gives: \[ n(n + 2) = (2.84)^2 \] - Calculating \( (2.84)^2 \): \[ (2.84)^2 = 8.0656 \] - Thus, we have: \[ n(n + 2) = 8.0656 \] 3. **Forming a Quadratic Equation**: - Rearranging gives: \[ n^2 + 2n - 8.0656 = 0 \] - We can use the quadratic formula \( n = \frac{-b \pm \sqrt{b^2 - 4ac}}{2a} \) where \( a = 1, b = 2, c = -8.0656 \). 4. **Calculating the Discriminant**: - First, calculate the discriminant: \[ b^2 - 4ac = 2^2 - 4 \cdot 1 \cdot (-8.0656) = 4 + 32.2624 = 36.2624 \] 5. **Finding the Roots**: - Now, substituting into the quadratic formula: \[ n = \frac{-2 \pm \sqrt{36.2624}}{2} \] - Calculating \( \sqrt{36.2624} \): \[ \sqrt{36.2624} \approx 6.02 \] - Thus: \[ n = \frac{-2 \pm 6.02}{2} \] - This gives us two possible values for \( n \): \[ n_1 = \frac{4.02}{2} = 2.01 \quad \text{(not valid since n must be an integer)} \] \[ n_2 = \frac{-8.02}{2} \quad \text{(not valid since n cannot be negative)} \] 6. **Analyzing the Given Configurations**: - Now we will analyze the options provided: - **Option 1: D4 in strong field**: All electrons paired → \( n = 0 \) (not valid). - **Option 2: D2 in weak field**: 2 unpaired electrons → \( n = 2 \) (valid). - **Option 3: D3 in weak field**: 3 unpaired electrons → \( n = 3 \) (not valid). - **Option 4: D5 in strong field**: 1 unpaired electron → \( n = 1 \) (not valid). 7. **Conclusion**: - The only configuration that yields 2 unpaired electrons is **Option 2: D2 in weak field**, which corresponds to the magnetic moment of `2.84 B.M.`. ### Final Answer: The correct configuration is **Option 2: D2 in weak field**.
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