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Select the incorrect match:...

Select the incorrect match:

A

`[Co(NO_(2))(H_(20O)(en)_(2)]Cl_(2),[CoCl(NO_(2))(en)_(2)]Cl*H_(2)O`: Hydrate isomerism

B

`[Cu(NH_(3))_(4)][PtCl_(4)],[CuCl(NH_(3))_(3)][}tCl_(3)(NH_(3))]`: Co-ordinatino isomersm

C

`[Ni(CN)(H_(2)O)(NH_(3))_(4)]Cl,[NiCl(H_(2)O)(NH_(3))_(4)]CN`: Ionization isomerism

D

`[Cr(NO_(2))(NH_(3))_(5)][ZnCl_(4)],[Cr(NO_(3))(NH_(3))_(5)][ZnCl_(4)]`: Linkage isomerism

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question of selecting the incorrect match among the given coordination compounds, we will analyze each option step by step. ### Step 1: Understand the Types of Isomers Before evaluating the options, let's briefly understand the types of isomers mentioned: 1. **Hydrate Isomers**: Isomers that differ in the number of water molecules inside and outside the coordination sphere. 2. **Coordination Isomers**: Isomers that differ in the arrangement of ligands around the central metal atom. 3. **Ionization Isomers**: Isomers that differ in the ions produced when the compound is dissolved in water. 4. **Linkage Isomers**: Isomers that differ in the way ligands are attached to the central metal atom. ### Step 2: Analyze Each Option 1. **Option A**: CO, NO2, H2O, En2O2, Cl2, Cu, Cl, NO2, En2O2, Cl.H2O - This option describes hydrate isomers. Since it involves the presence of water molecules, it is correctly matched. 2. **Option B**: CONH3O4, PTCl4 and COClNH3O3, PTCl3NH3 - This option describes coordination isomers. The ligands are arranged differently around the central metal, making this a correct match. 3. **Option C**: Ni-Cl-H2O-NH3O4-Cl and Ni-Cl-H2O-NH3O4-Cl - This option claims to be ionization isomers. However, since both compounds are identical, they cannot be ionization isomers. Therefore, this option is incorrect. 4. **Option D**: CrNO2NH3O5 and ZnCl4, CrNO2NH3O5ZnCl4 - This option suggests linkage isomers. However, the ligands are not merely rearranged but differ in their chemical composition (NO2 vs NO3), which means they cannot be classified as isomers. This option is also incorrect. ### Conclusion After analyzing all options, we find that: - **Option C** is the incorrect match as it does not represent ionization isomers, but rather the same compound. ### Final Answer The incorrect match is **Option C**.

To solve the question of selecting the incorrect match among the given coordination compounds, we will analyze each option step by step. ### Step 1: Understand the Types of Isomers Before evaluating the options, let's briefly understand the types of isomers mentioned: 1. **Hydrate Isomers**: Isomers that differ in the number of water molecules inside and outside the coordination sphere. 2. **Coordination Isomers**: Isomers that differ in the arrangement of ligands around the central metal atom. 3. **Ionization Isomers**: Isomers that differ in the ions produced when the compound is dissolved in water. 4. **Linkage Isomers**: Isomers that differ in the way ligands are attached to the central metal atom. ...
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VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-LEVEL 2
  1. Select the correct code of TRUE and FALSE for given statements: (a) ...

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  2. The total possible co-ordination isomers for the following compounds r...

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  3. Select the incorrect match:

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  4. Select the correct code about complex [Cr(NO(2))(NH(3))(5)][ZnCl(4)]: ...

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  5. The magnetic property, dipole moment, plane of symmetry, colour and ab...

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  6. Which of the following isomerism is not possible for complexes having ...

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  7. Unmatched characteristic of complex [PdCl(2)(H(2)O)(2)(NH(3))(2)]^(2+)...

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  8. Which one of the following has largest number of isomers ? (R = alkyl ...

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  9. Which one of the following complexes exhibit chirality?

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  10. Consider the following isomerism: (i) Ionization (ii) Hydrate (i...

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  11. Which complex is likely to show optical activity :

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  12. Which of the following statement is true?

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  13. The following complexs are given? trans-[Co(NH(3))(4)1(2)]^(o+) ci...

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  14. Which of the following can show geometrical isomerism?

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  15. Which of the following compounds will exhibit cis-trans (geometrical) ...

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  16. Which of the following will have two stereoisomeric forms? (I) [Cr(N...

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  17. A coordination complex of type MX(2)Y(2) (M-metal ion: X, Y-monodentat...

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  18. The ratio of cis and trans-isomers of the complex [Ma(2)bcde]^(n+-) is...

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  19. [PdCl(2)(PM e(3))(2)] is a diamagnetic complex of Pd (II). How many un...

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  20. Complex compounds(s) which is optical active and does ot dpeend upon t...

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