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Complex compounds(s) which is optical ac...

Complex compounds(s) which is optical active and does ot dpeend upon the orientation of the ligands around metal cation:
(i) `[CoCl_(3)(NH_(3))_(3)]`
(ii) `[Co(en)_(3)]Cl_(3)`
(iii) `[Co(C_(2)O_(4))_(2)(NH_(3))_(2)]^(-)`
(iv) `[CrCl_(2)(NH_(3))_(2)(en)]^(+)`

A

(ii), (iii) and (iv)

B

(i), (ii) and (iv)

C

(ii) and (iv)

D

only (ii)

Text Solution

Verified by Experts

The correct Answer is:
A


Hence, orientation of ligands determine asymmetric nature of the complex.
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Which of the following will have three stereoisomeric forms? (i) [Cr(NO_(3))_(3)(NH_(3))_(3)] (ii) K_(3)[Co(C_(2)O_(4))_(3)] (iii) K_(3)[CoCl_(2)(C_(2)O_(4))_(2)] (iv) [CoBrCl(en)_(2)]

Draw all the isomers (geometrical and optical) of: (i) [CoCl_(2)(en)_(2)]^(+) (ii) [Co(NH_(3))Cl(en)_(2)]^(2+) (iii) [Co(NH_(3))_(2)Cl_(2)(en)]^(+)

The compound [CrCl_(2)(NH_(3))_(2)(en)] can form .

Which of the following can exhibit geometrical isomerism ? [Co(NH_(3))_(4)Cl_(2))] [Co(en)_(3)]Cl_(2) [Co(en)_(2)(NO_(2))aCl]SCN [Co(NH_(3)_(6)][Cr(CN)_(6)]

Which of the following can exhibit optical isomerism: (i) [Cr(gly)_3]^0 (ii) [CoBr_(2)CI_(2)(SCN)_(2)]^(3-) (iii) [Co(en)_(3)]^(3+) (iv) Na[PtBrCI(NO_(2))(NH_(3))]

Arrange the following compounds in order of increasing molar conductivity . (i) K[Co(NH_(3))_(2)(NO_(2))_(4)]" " (ii) [Cr(NH_(3))_(3)(NO_(2))_(3)] (iii) [Cr(NH_(3))_(5)(NO_(2))]_(3)[Co(NO_(2))_(6)]_(2)" " (iv) [Cr(NH_(3))_(6)]Cl_(3)

Indicate the type of isomerism exhibited by the following complexes and draw the structures for these isomers: (i) K[Cr(H_(2)O)_(2)(C_(2)O_(4))_(2) (ii) [Co(en)_(3)]Cl_(3) (iii) [Co(NH_(3))_(5)(NO_(2))](NO_(3))_(2) (iv) [Pt(NH_(3))(H_(2)O)Cl_(2)]

The total possible co-ordination isomers for the following compounds respectively are (i) [Co(en)_(3)][Cr(C_(2)O_(4))_(3)] (ii) [Cu(NH_(3))_(4)][CuCl_(4)] (iii) [Ni(en)_(3)][Co(NO_(2))_(6)]

Give the IUPAC names of the following compounds : (i) [Co(NH_3)_(4)(H_(2)O)Cl]CL_2 (ii) [CrCl_2(en)_2]Cl

The hybridization of the complex [CrCl_(2)(NO_(2))_(2)(NH_(3))_(2)]^(-) is:

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