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Which of the followingg statement(s) is/...

Which of the followingg statement(s) is/are false?

A

In `[PtCl_(2)(NH_(3))_(4)]^(2+)` complex ion, the cis-form is optically active, while trans-form is optically inactive

B

In `[Fe(C_(2)O_(4))_(3)]^(3-)`, geometrical isomerism does not exist, while optical isomerism exist

C

In `[Mabcd]^(n+-)` tetrahedral complexes, optical isomerism cannot be observed

D

In `[Mabcd]^(n+-)` square planar complex, optical isomerism can be observed

Text Solution

Verified by Experts

The correct Answer is:
A, C, D

`[PtCl_(2)(NH_(3))_(4)]^(2+)implies` both cis and trans forms are optically inacctive
(b)
`implies`Due to asymmetrical configuration, it exhibits optical isomerism.
(c)
`implies`Due to plane of symmetry does not exhibit optical isomerism, but exhibits geometrical isomerism.
(d)
`implies`Tetrahedral complex, asymmetric configuration, hence exhibits optical isomerism.
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