Home
Class 12
CHEMISTRY
Select the correct statement:...

Select the correct statement:

A

Chelation effect is maximum for five and six membered rings

B

Greater the charge on the central metal cation, greater the value of `Delta(CFSE)`

C

In complex ion `[CoF_(6)]^(3-),F^(-)` is a weak field ligand, so that `Delta_(oct) lt P`(Pairng energy) and it is low spin complex

D

`[CoCl_(2)(NH_(3))_(2)(en)]^(o+)` complex ion will have four different isomers

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze each statement provided in the video transcript and determine which ones are correct. ### Step-by-Step Solution: 1. **Statement 1: Chelation effect is maximum for 5 and 6 membered rings.** - **Analysis:** The chelation effect refers to the increased stability of a complex due to the formation of rings involving the metal ion and the ligands. It is well-established that 5 and 6 membered rings provide optimal stability due to favorable geometric and electronic factors. Therefore, this statement is **true**. 2. **Statement 2: Greater the charge on the central metal cation, greater is the value of crystal field stabilization energy (CFSE).** - **Analysis:** The crystal field stabilization energy increases with the positive charge on the central metal ion because a higher charge leads to a stronger attraction between the metal ion and the ligands. This results in greater splitting of the d-orbitals and thus higher CFSE. Therefore, this statement is also **true**. 3. **Statement 3: In complex ions COF6^3-, fluoro is a weak field ligand, so that splitting energy of octahedral is less than pairing energy and it is a low spin type complex.** - **Analysis:** Fluoride (F-) is indeed a weak field ligand, which means that it does not cause significant splitting of the d-orbitals. In this case, the pairing energy is greater than the splitting energy, leading to a high spin complex where electrons remain unpaired. Therefore, this statement is **false**. 4. **Statement 4: COCl2(NH3)(EN) complex will have four different isomers.** - **Analysis:** The complex COCl2(NH3)(EN) can exhibit geometric isomerism (cis and trans) and optical isomerism due to the presence of the bidentate ligand (EN). This results in a total of four isomers: two optical isomers (cis) and two geometrical isomers (trans). Therefore, this statement is **true**. ### Conclusion: The correct statements are: - Statement 1: True - Statement 2: True - Statement 3: False - Statement 4: True Thus, the correct options are **A, B, and D**.

To solve the question, we need to analyze each statement provided in the video transcript and determine which ones are correct. ### Step-by-Step Solution: 1. **Statement 1: Chelation effect is maximum for 5 and 6 membered rings.** - **Analysis:** The chelation effect refers to the increased stability of a complex due to the formation of rings involving the metal ion and the ligands. It is well-established that 5 and 6 membered rings provide optimal stability due to favorable geometric and electronic factors. Therefore, this statement is **true**. 2. **Statement 2: Greater the charge on the central metal cation, greater is the value of crystal field stabilization energy (CFSE).** ...
Promotional Banner

Topper's Solved these Questions

  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise MATCH THE COLUMN|36 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|26 Videos
  • CO-ORDINATION COMPOUNDS

    VK JAISWAL ENGLISH|Exercise LEVEL 3 (PASSAGE TYPE)|98 Videos
  • CHEMICAL BONDING (BASIC)

    VK JAISWAL ENGLISH|Exercise SUBJECTIVE PROBLEMS|54 Videos
  • d-BLOCK ELEMENTS

    VK JAISWAL ENGLISH|Exercise ASSERTION-REASON TYPE QUESTIONS|32 Videos

Similar Questions

Explore conceptually related problems

Selecte the correct statement.

Select a correct statement

VK JAISWAL ENGLISH-CO-ORDINATION COMPOUNDS-ONE OR MORE ANSWERS IS/ARE CORRECT
  1. Which of the followingg statement(s) is/are false?

    Text Solution

    |

  2. Which of the following statement(s) is/are true?

    Text Solution

    |

  3. Select the correct statement:

    Text Solution

    |

  4. Which of the following statement(s) is/are true?

    Text Solution

    |

  5. In test of NO(3)^(-) ion, the dark brown ring complex is formed, which...

    Text Solution

    |

  6. The complex(es) which is/are blue in colour:

    Text Solution

    |

  7. What is/are the coordination number(s) of Au in the complexes formed b...

    Text Solution

    |

  8. The d-orbitals involved in sp^(3)d^(2) or d^(2)sp^(3) hybridization of...

    Text Solution

    |

  9. Which is not correctly matched?

    Text Solution

    |

  10. Which of the following statement(s) is(are) correct?

    Text Solution

    |

  11. Which is/are correct statement(s)?

    Text Solution

    |

  12. Consider the following two reactions: Cd^(2+)(aq.)+4CH(3)NH(2) overs...

    Text Solution

    |

  13. Complex compound [Co(SCN)(2)(NH(3))(4)]Cl exhibits:

    Text Solution

    |

  14. Which of the following compound has/have effective atomic number equal...

    Text Solution

    |

  15. Select correct statement(s) regarding octahedron complex having CFSE=-...

    Text Solution

    |

  16. Consider the following two carbonyl compounds (i) [Tc(CO)(6)]^(+) an...

    Text Solution

    |

  17. Which of the following ligand does not as pi-acid ligand?

    Text Solution

    |

  18. Find out correct IUPAC name of complex compound

    Text Solution

    |

  19. Consider the following reactions of complex compounds A,B and C (i) ...

    Text Solution

    |

  20. Which complex species does/do not exhibit geometrical and only have tw...

    Text Solution

    |