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Assertion: [Fe(EDTA)]^(-) complex is oct...

Assertion: `[Fe(EDTA)]^(-)` complex is octahedral in shape.
Reason: EDTA is a hexadentate ligand and undergoing `sp^(3)d^(2)` hybridisation.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze both the assertion and the reason provided regarding the `[Fe(EDTA)]^(-)` complex. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the `[Fe(EDTA)]^(-)` complex is octahedral in shape. - EDTA (Ethylenediaminetetraacetic acid) is a hexadentate ligand, meaning it can coordinate to a metal ion through six donor atoms (four carboxylate oxygen atoms and two amine nitrogen atoms). - When a hexadentate ligand like EDTA coordinates to a metal ion such as Fe, it occupies six coordination sites around the metal, leading to an octahedral geometry. **Conclusion**: The assertion is correct. 2. **Understanding the Reason**: - The reason states that EDTA is a hexadentate ligand and undergoes `sp^(3)d^(2)` hybridization. - While it is true that EDTA is a hexadentate ligand, the hybridization mentioned is incorrect. - In the case of strong field ligands like EDTA, the hybridization that occurs is actually `d^(2)sp^(3)`, not `sp^(3)d^(2)`. This is because the d-orbitals are involved in the hybridization process to accommodate the strong field effect and pairing of electrons. **Conclusion**: The reason is incorrect. 3. **Final Evaluation**: - Since the assertion is correct and the reason is incorrect, we conclude that the statement is partially true. The `[Fe(EDTA)]^(-)` complex is indeed octahedral, but the hybridization described in the reason is not accurate. ### Summary: - **Assertion**: Correct - **Reason**: Incorrect

To solve the given question, we need to analyze both the assertion and the reason provided regarding the `[Fe(EDTA)]^(-)` complex. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the `[Fe(EDTA)]^(-)` complex is octahedral in shape. - EDTA (Ethylenediaminetetraacetic acid) is a hexadentate ligand, meaning it can coordinate to a metal ion through six donor atoms (four carboxylate oxygen atoms and two amine nitrogen atoms). - When a hexadentate ligand like EDTA coordinates to a metal ion such as Fe, it occupies six coordination sites around the metal, leading to an octahedral geometry. ...
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