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Assertion: Zeise's salt is a pi-bonded o...

Assertion: Zeise's salt is a `pi`-bonded organometallic compound.
Reason: Zeise's salt contain `C_(2)H_(4)` molecules as one of the ligand.

A

If assertion is true but the reason is false

B

If assertion is false but reason is true

C

If both assertion and reason are true and the reason is the correct explanation of assertion

D

If both assertion and reason are true but reason is not the correct explanation of assertion

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding Zeise's salt, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Assertion The assertion states that "Zeise's salt is a π-bonded organometallic compound." - **Definition**: An organometallic compound is one that contains a bond between a carbon atom of an organic molecule and a metal. In the case of Zeise's salt, it is composed of potassium (K), platinum (Pt), and an ethylene ligand (C2H4). - **π-bonding**: The ethylene (C2H4) ligand has a double bond (C=C), which can interact with the metal center (Pt) through π-bonding. This means that the π electrons from the ethylene can be donated to the metal, forming a bond. ### Conclusion for Step 1 Since Zeise's salt contains both an organic component (C2H4) and a metal (Pt), and the ethylene ligand is π-bonded to the platinum, the assertion is correct. ### Step 2: Understanding the Reason The reason states that "Zeise's salt contains C2H4 molecules as one of the ligands." - **Ligand Identification**: In the structure of Zeise's salt, we can identify that it indeed contains C2H4 as a ligand. The ethylene molecule acts as a ligand that coordinates to the platinum center. - **Structure**: The structure of Zeise's salt can be represented as K[PtCl3(C2H4)], where C2H4 is coordinated to the platinum. ### Conclusion for Step 2 Since the reason accurately describes the presence of the C2H4 ligand in Zeise's salt, the reason is also correct. ### Final Conclusion Both the assertion and the reason are correct, and the reason provides a correct explanation for the assertion. ### Summary - **Assertion**: Correct (Zeise's salt is a π-bonded organometallic compound). - **Reason**: Correct (Zeise's salt contains C2H4 molecules as one of the ligands). - **Relationship**: The reason is a correct explanation of the assertion.
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The N_(2)H_(4) molecule contains :

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